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Publications

Publications by CAP

2023

Scalable and Cost-Effective All-Chemical Production of Stable Gold-Coated Silver Thin-Films for High-Performance Plasmonic Optical Fiber Sensors

Authors
dos Santos, SS; Mendes, P; Pastoriza Santos, I; de Almeida, MMM; Coelho, CC;

Publication
Proceedings - 28th International Conference on Optical Fiber Sensors, OFS 2023

Abstract
Long-term stability and high scalability are significant issues in plasmonic optical fiber sensors. This work presents a highly scalable and low-cost all-chemical approach for production of gold-coated silver thin-films, ensuring high performance and chemical stability. © Optica Publishing Group 2023, © 2023 The Authors.

2023

A field-based evaluation of portable XRF to screen for toxic metals in seafood products

Authors
Roberts, AA; Guimaraes, D; Tehrani, MW; Lin, S; Parsons, PJ;

Publication
X-RAY SPECTROMETRY

Abstract
Portable X-Ray Fluorescence (XRF) has become increasingly popular where traditional laboratory methods are either impractical, time consuming, and/or too costly. While the Limit of Detection (LOD) is generally poorer for XRF compared to laboratory-based methods, recent advances have improved XRF LODs and increased its potential for field-based studies. Portable XRF can be used to screen food products for toxic elements such as lead (Pb), cadmium (Cd), mercury (Hg), arsenic (As), manganese, (Mn), zinc (Zn), and strontium (Sr). In this study, 23 seafood samples were analyzed using portable XRF in a home setting. After XRF measurements were completed in each home, the same samples were transferred to the laboratory for re-analysis using microwave-assisted digestion and Inductively Coupled Plasma Tandem Mass Spectrometry (ICP-MS/MS). Four elements (Mn, Sr, As, and Zn) were quantifiable by XRF in most samples, and those results were compared to those obtained by ICP-MS/MS. Agreement was judged reasonable for Mn, Sr, and As, but not for Zn. Discrepancies could be due to (1) the limited time available to prepare field samples for XRF, (2) the heterogeneous nature of real samples analyzed by XRF, and (3) the small beam spot size (similar to 1 mm) of the XRF analyzer. Portable XRF is a cost-effective screening tool for public health investigations involving exposure to toxic metals. It is important for practitioners untrained in XRF spectrometry to (1) recognize the limitations of portable instrumentation, (2) include validation data for each specific analyte(s) measured, and (3) ensure personnel have some training in sample preparation techniques for field-based XRF analyses.

2023

Erbium-doped fiber ring cavity for the measurement of refractive index variations

Authors
Perez Herrera, RA; Soares, L; Novais, S; Frazão, O; Silva, S;

Publication
Proceedings of SPIE - The International Society for Optical Engineering

Abstract

2023

White Light Interferometry: Absolute and High Precision Measurement for Long-Cavity Fibre Fabry-Perot Sensors

Authors
Robalinho, P; Rodrigues, A; Novais, S; Ribeiro, ABL; Silva, S; Frazão, O;

Publication
EPJ Web of Conferences

Abstract
White Light Interferometry, known for its absolute measurement capability and high precision, had its greatest scientific impact towards the end of the 20th century. In this work, it was assembled and characterized a fibre Mach-Zehnder interferometer (MZI) as an interrogator and a fibre Fabry-Perot interferometer (FPI) as a displacement sensor. A measurement bandwidth between 65 µm and 95 µm was obtained for FPI cavities close to 2.35 mm, at sampling frequencies between 600 Hz and 1500 Hz. Additionally, a resonant frequency at 550 Hz was achieved, allowing for an interrogation band higher than 135 µm. It was also determined a minimum absolute resolution of ± 66 nm, corresponding to a relative resolution of ± 9.4×10-4 in relation to the total band.

2023

Erbium-doped fiber ring cavity assisted by an FBG and PS-FBG reflector for refractive-index measurements - INVITED

Authors
Perez-Herrera, RA; Diaz, H; Soares, L; Novais, S; Lopez-Amo, M; Silva, S; Frazão, O;

Publication
EPJ Web of Conferences

Abstract
This work presents an interrogator system based on an erbium-doped fiber ring cavity for refractive-index measurements. This fiber ring cavity is assisted by a fiber Bragg grating and a phase-shift fiber Bragg grating, both with a similar central emission wavelength to increase the output power levels.

2022

Tunable Plasmonic Resonance Sensor Using a Metamaterial Film in a D-Shaped Photonic Crystal Fiber for Refractive Index Measurements

Authors
Cardoso, MP; Silva, AO; Romeiro, AF; Giraldi, MTR; Costa, JCWA; Santos, JL; Baptista, JM; Guerreiro, A;

Publication
APPLIED SCIENCES-BASEL

Abstract
Subwavelength cells of metallic nanorods arrayed in a dielectric background, termed "metamaterials", present bulk properties that are useful to control and manipulate surface plasmon resonances. Such feature finds tremendous potential in providing a broad manifold of applications for plasmonic optical sensors. In this paper, we propose a surface-plasmon-resonance-based sensor with spectral response tunable by the volume fraction of silver present in a metamaterial layer deposited on a D-shaped photonic crystal fiber. Using computational simulations, we show that sensitivity and resolution can be hugely altered by changing the amount of constituents in the metamaterial, with no further modifications in the structure of the sensor. Moreover, the designed sensor can also be applied to label the average volume fraction of silver in the metamaterial layer and then to estimate its effective constitutive parameters.

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