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Publications

Publications by CAP

2024

Temperature Dependence of the Thermo-Optic Coefficient of GeO2-Doped Silica Glass Fiber

Authors
Rego, GM;

Publication
Sensors

Abstract
In this paper we derived an expression that allows the determination of the thermo-optic coefficient of weakly-guiding germanium-doped silica fibers, based on the thermal behavior of optical fiber devices, such as, fiber Bragg gratings (FBGs). The calculations rely on the full knowledge of the fiber parameters and on the temperature sensitivity of FBGs. In order to validate the results, we estimated the thermo-optic coefficient of bulk GeO2 glass at 293 K and 1.55 µm to be 18.3 × 10-6 K-1. The determination of this value required to calculate a correction factor which is based on the knowledge of the thermal expansion coefficient of the fiber core, the Pockels’ coefficients (p11 = 0.125, p12 = 0.258 and p44 = -0.0662) and the Poisson ratio (? = 0.161) of the SMF-28 fiber. To achieve that goal, we estimated the temperature dependence of the thermal expansion coefficient of GeO2 and we discussed the dispersion and temperature dependence of Pockels’ coefficients. We have presented expressions for the dependence of the longitudinal and transverse acoustic velocities on the GeO2 concentration used to calculate the Poisson ratio. We have also discussed the dispersion of the photoelastic constant. An estimate for the temperature dependence of the thermo-optic coefficient of bulk GeO2 glass is presented for the 200–300 K temperature range. © 2024 by the author.

2024

Study on fs-laser machining of optical waveguides and cavities in ULE® glass

Authors
Maia, JM; Marques, PVS;

Publication
JOURNAL OF OPTICS

Abstract
The potential of ultrafast laser machining for the design of integrated optical devices in ULE (R) glass, a material known for its low coefficient of thermal expansion (CTE), is addressed. This was done through laser direct writing and characterization of optical waveguides and through the fabrication of 3D cavities inside the glass by following laser irradiation with chemical etching. Type I optical waveguides were produced and their internal loss mechanisms at 1550 nm were studied. Coupling losses lower than 0.2 dB cm-1 were obtained within a wide processing window. However, propagation loss lower than 4.2-4.3 dB cm-1 could not be realized, unlike in other glasses, due to laser-induced photodarkening. Selective-induced etching was observed over a large processing window and found to be maximum when irradiating the glass with a fs-laser beam linearly polarised orthogonally to the scanning direction, akin to what is observed in fused silica laser-machined microfluidic channels. In fact, the etching selectivity and surface roughness of laser-machined ULE (R) glass was found to be similar to that of fused silica, allowing some of the already reported microfluidic and optofluidic devices to be replicated in this low CTE glass. An example of a 3D cavity with planar-spherically convex interfaces is given. Due to the thermal properties of ULE (R) glass, these cavities can be employed as interferometers for wavelength and/or temperature referencing.

2024

High-visibility Fabry-P<acute accent>erot interferometer fabricated in ULE® glass through fs-laser machining

Authors
Maia, JM; Marques, PVS;

Publication
OPTICS AND LASER TECHNOLOGY

Abstract
Low-finesse Fabry-Perot interferometers (FPI) with a plano-convex geometry are fabricated in ULE (R) glass through ultrafast laser machining. With this geometry, it is possible to overcome beam divergence effects that contribute to the poor fringe visibility usually observed in 100-mu m or longer planar-planar FPIs. By replacing the planar surface with a spherical one, the diverging beam propagating through the cavity is re-focused back at the entrance of the lead-in fiber upon reflection at this curved interface, thereby balancing out the intensities of both interfering beams and enhancing the visibility. The design of a 3D shaped cavity with a spherical sidewall is only made possible through fs-laser direct writing followed by chemical etching. In this technique, the 3D volume is reduced to writing of uniformly vertically spaced 2D layers with unique geometry, which are then selectively removed during chemical etching with HF acid. The radius of curvature that maximizes fringe visibility is computed using a numerical tool that is experimentally validated. By choosing the optimal radius of curvature, uniform visibilities in the range of 0.98-1.00 are measured for interferometers produced with cavity lengths spanning from 100 to 1000 mu m.

2024

Integrated All-In-Silica Optofluidic Platform Based on Microbubble Resonator and Femtosecond Laser Written Surface Waveguide

Authors
Amorim, VA; Frigenti, G; Baldini, F; Berneschi, S; Farnesi, D; Jorge, PAS; Maia, JM; Conti, GN; dos Santos, PSS; Marques, PVS;

Publication
IEEE SENSORS JOURNAL

Abstract
Optical microbubble resonators (OMBRs)-understood as localized thin wall bulges induced in silica microcapillaries-are gaining an ever-growing interest in microfluidic sensing applications due to their capability to sustain whispering gallery modes (WGMs) and confine the fluidic sample within their own hollow-core microcavity. Currently, most applications use an external tapered optical fiber for coupling light to the resonator. This arrangement is known to be fragile and prone to vibrations. In this work, an alternative approach, based on coupling OMBR with a femtosecond (fs) laser-written optical waveguides, integrated at the surface of fused silica substrate, is proposed. In this configuration, a stable and robust final structure is accomplished by gluing the two ends of the microcapillary, on which the OMBR is made, to the substrate. The OMBR quality factors, measured at the excitation wavelength of 1540 nm, show values close to 10(4) in the case of a water-filled cavity, with a maximum coupling efficiency of up to 6.5%. Finally, the operation of the integrated optical devices as refractometers is demonstrated by delivering different solutions with successively increasing concentrations of NaCl inside the OMBR. An average sensitivity of 45 nm/RIU is obtained, yielding a resolution of 4.4x10(-5) RIU, creating the potential for this platform to be applied in chemical/biochemical sensing.

2024

Exploring new phenomena in analogue physical simulations through an optical feedback loop in paraxial light fluids

Authors
Ferreira, TD; Guerreiro, A; Silva, NA;

Publication
NONLINEAR OPTICS AND ITS APPLICATIONS 2024

Abstract
Exploring optical analogues with paraxial fluids of light has been a subject of great interest over the past years. Despite many optical analogues having been created and explored with these systems, they have some limitations that usually hinder the observation of the desired dynamics. Since these systems map the effective time onto the propagation direction, the fixed size of the nonlinear media limits the experimental effective time, and only the output state is accessible. In this work, we present a solution to overcome these problems in the form of an optical feedback loop, which consists of reconstructing the output state, by using the off-axis digital holography technique, and then re-injecting it again at the entrance of the medium through the utilization of Spatial Light Modulators. This technique enables access to intermediate states and an extension of the system effective time. Furthermore, the total control of the amplitude and phase of the beam at the input of the medium, also allows us to explore more exotic configurations that may be interesting in the context of optical analogues, that otherwise would be hard to create. To demonstrate the capabilities of the setup, we explore qualitatively some case studies, such as the dark soliton decay into vortices with the propagation of shock waves, and the collision dynamics between three flat-top states. The results presented in this work pave the way for probing new dynamics with paraxial fluids of light.

2024

Impact of gaseous interferents on palladium expansion for hydrogen optical sensing: A time stability study

Authors
Almeida, MAS; Almeida, JMMMD; Coelho, LCC;

Publication
OPTICS AND LASER TECHNOLOGY

Abstract
Continuous monitoring of hydrogen (H2) concentration is critical for safer use, which can be done using optical sensors. Palladium (Pd) is the most commonly used transducer material for this monitoring. This material absorbs H2 leading to an isotropic expansion. This process is reversible but is affected by the interaction with interferents, and the lifetime of Pd thin films is a recurring issue. Fiber Bragg Grating (FBG) sensors are used to follow the strain induced by H2 on Pd thin films. In this work, it is studied the stability of Pd-coated FBGs, protected with a thin Polytetrafluoroethylene (PTFE) layer, 10 years after their deposition to assess their viability to be used as H2 sensors for long periods of time. It was found that Pd coatings that were PTFE-protected after deposition had a longer lifetime than unprotected films, with the same sensitivities that they had immediately after their deposition, namely 23 and 10 pm/vol% for the sensors with 150 and 100 nm of Pd, respectively, and a saturation point around 2 kPa. Furthermore, the Pd expansion was analyzed in the presence of H2, nitrogen (N2), carbon dioxide (CO2), methane (CH4) and water vapor (H2O), finding that H2O is the main interferent. Finally, an exhaustive test for 90 h is also done to analyze the long-term stability of Pd films in dry and humid environments, with only the protected sensor maintaining the long-term response. As a result, this study emphasizes the importance of using protective polymeric layers in Pd films to achieve the five-year lifetime required for a real H2 monitoring application.

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