Abstract
Reinforced concrete structures are prevalent in infrastructure and are of significant economic and social importance to humanity. However, they are prone to decay from cement paste carbonation. pH sensors have been developed to monitor cement paste carbonation, but their adoption by the industry remains limited. This work introduces two new methods for monitoring cement paste carbonation in real time that have been validated through the accelerated carbonation of cement paste samples. Both configurations depart from traditional pH monitoring. In the first configuration, the carbonation depth of a cement paste sample is measured using two CO2 optical fiber sensors. One sensor is positioned on the surface of the sample, while the other is embedded in the middle. As the carbonation depth progresses and reaches the embedded CO2 sensor, the combined response of the sensors changes. In the second configuration, a multimode fiber is embedded within the paste, and its carbonation is monitored by observing the increase in reflected light intensity (1.6-18%) resulting from the formation of CaCO3. Its applicability in naturally occurring carbonation is tested at concentrations of 3.2% CO2, and the influence of water is positively evaluated; thus, this setup is suitable for real-world testing and applications.

Abstract

Abstract

Abstract

Abstract
The values of measured and calculated spectroscopic quantities of lithium niobate doped with rare earth and transition metal ions, such as polarized emission and absorption cross sections, variation of fluorescence life time with temperature and concentration of the dopant, Judd-Ofelt coefficients, non-radiative transition probabilities and energy levels are presented. Wherever published data is available, comparison with measured or calculated data presented in this work is carried out. The theories utilized in the interpretation of the experimental results, such as Judd-Ofelt theory, Fuchtbauer-Lademburg relation and McCumber theory are summarily presented.

Abstract
The purpose of this work was to develop a design methodology for the fabrication of proton exchanged channel waveguides in LiNbO3 operating in the singlemode regime at several wavelengths, with specific characteristics required to optimize integrated devices. To achieve this, it is necessary to obtain the relations between the optical characteristics of the waveguides and their respective fabrication conditions, and to introduce models of the waveguide formation process. The relations between fabrication conditions and optical characteristics of planar waveguides realized by proton exchange in benzoic acid are documented extensively in the literature. However, reports on the characterization of waveguide fabrication processes, performed in a systematic way, could not be found, resulting in the need to combine information from several sources. Discrepancies among results from different researches are evident, resulting from different experimental methodologies and calibration of equipment. Therefore, aiming at extracting a consistent data set, optical characterization techniques of the refractive index profile were employed to study series of samples.