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Publications

Publications by Pedro Jorge

2021

Spectral Reconstruction and Bayesian Model Framework for Characterization of Long Period Fiber Gratings

Authors
Dias, B; Santos, P; Jorge, PAS; de Almeida, JMMM; Coelho, LCC;

Publication
IEEE INSTRUMENTATION & MEASUREMENT MAGAZINE

Abstract
The use of Long-Period Fiber Gratings (LPFGs) as sensors has been thoroughly researched, given the multitude of parameters these structures can monitor by themselves (such as temperature, strain, curvature) and the potential for combination with other materials that allow for monitoring of parameters such as humidity, pH and chemical concentration, at a low price and with easy fabrication processes available. This interest has increased the need for the development of interrogation systems for these sensors, particularly in the C-band spectral region. Given the cost and physical limitations (such as size and weight) of traditional solutions like Optical Spectrum Analyzers (OSA), the development of low-cost approaches for LPFG spectral analysis became an important topic that needed further development. The development of a simple curve fitting routine for LPFG spectra is reported in this article, along with a framework for automatic detection of certain physical phenomena such as corrosion and the presence of chemical species, among others.

2021

Particle Classification through the Analysis of the Forward Scattered Signal in Optical Tweezers

Authors
Carvalho, IA; Silva, NA; Rosa, CC; Coelho, LCC; Jorge, PAS;

Publication
SENSORS

Abstract
The ability to select, isolate, and manipulate micron-sized particles or small clusters has made optical tweezers one of the emergent tools for modern biotechnology. In conventional setups, the classification of the trapped specimen is usually achieved through the acquired image, the scattered signal, or additional information such as Raman spectroscopy. In this work, we propose a solution that uses the temporal data signal from the scattering process of the trapping laser, acquired with a quadrant photodetector. Our methodology rests on a pre-processing strategy that combines Fourier transform and principal component analysis to reduce the dimension of the data and perform relevant feature extraction. Testing a wide range of standard machine learning algorithms, it is shown that this methodology allows achieving accuracy performances around 90%, validating the concept of using the temporal dynamics of the scattering signal for the classification task. Achieved with 500 millisecond signals and leveraging on methods of low computational footprint, the results presented pave the way for the deployment of alternative and faster classification methodologies in optical trapping technologies.

2021

X-ray Fluorescence and Laser-Induced Breakdown Spectroscopy Analysis of Li-Rich Minerals in Veins from Argemela Tin Mine, Central Portugal

Authors
Ribeiro, R; Capela, D; Ferreira, M; Martins, R; Jorge, P; Guimaraes, D; Lima, A;

Publication
MINERALS

Abstract
In this work, X-ray fluorescence (XRF) and Laser-induced breakdown spectroscopy (LIBS) analyses were applied to samples of quartz, montebrasite, and turquoise hydrothermal veins in the Argemela Tin Mine (Central Portugal). Montebrasite (LiAl(PO4)(OH,F)) is potentially the main ore mineral; with its alteration, lithium (Li) can disseminate into other minerals. A hand sample was cut and analyzed by XRF and LIBS for several elements of interest including Cu, P, Al, Si, and Li. Although XRF cannot measure Li, results from its analysis are effective for distinguishing turquoise from montebrasite. LIBS analysis complemented this study, making it possible to conclude that turquoise does not contain any significant Li in its structure. The difference in spot size between the techniques (5 mm vs. 300 mu m for XRF and LIBS, respectively) resulted in a poorer performance by XRF in accurately identifying mixed minerals. A thin section was petrographically characterized and mapped using LIBS. The mapping results demonstrate the possibility of the successful identification of minerals and their alterations on a thin section. The results of XRF analysis and LIBS mapping in petrographic sections demonstrate the efficacy of these methods as tools for element and mineral identification, which can be important in exploration and mining phases, complementing more traditional techniques.

2021

(INVITED)Classification of optically trapped particles: A comparison between optical fiber tweezers and conventional setups

Authors
Jorge, PAS; Carvalho, IA; Marques, FM; Pinto, V; Santos, PH; Rodrigues, SM; Faria, SP; Paiva, JS; Silva, NA;

Publication
Results in Optics

Abstract
The classification of the type of trapped particles is a crucial task for an efficient integration of optical-tweezers in intelligent microfluidic devices. In the recent years, the use of the temporal scattering signal of the trapped particle paved for the use of versatile optical fiber solutions for performing such tasks, a feature previously unavailable as most methods required conventional optical tweezer setups. This work presents a comprehensive comparison of performances achieved with two distinct implementations – i)optical fiber and ii)conventional optical tweezers – for the classification of the material of particles through the analysis of the scattering signal with machine learning algorithms. The results suggest that while micron-sized particles can be accurately classified using the forward scattering information in conventional optical tweezers, when equipped with a quadrant photodetector, the optical fiber tweezers solutions can easily surpass its performance using the back-scattered information if the laser is modulated. Together with the advantages of being simpler, less expensive and more versatile, the results presented suggest that optical fiber solutions can become a valuable tool for miniaturization and integration of intelligent microfluidic devices working towards nanoscopic scales. © 2021 The Authors

2021

Label-Free Anti-Human IgG Biosensor Based on Chemical Modification of a Long Period Fiber Grating Surface

Authors
Mendes, JP; Coelho, LCC; Pereira, VP; Azenha, MA; Jorge, PAS; Pereira, CM;

Publication
Chemistry Proceedings

Abstract
This work introduces a method specially developed to produce a biorecognition element based on modified Stöber silica nanoparticles by the covalent immobilization of the human IgG. The sensing structure is based on long period fiber gratings (LPFG), specially developed to allow the interaction of the electromagnetic wave with the target analytes through its evanescent field. The surface was modified by the immobilization of the IgG-modified nanoparticles serving has recognition elements for specific target molecules. The resulting configuration was tested in the presence of anti-human IgG, recording the refractometric response of the modified LPFG in contact with different amounts of analyte. The selectivity of the sensor was also assessed.

2021

Optical Biosensor for the Detection of Hydrogen Peroxide in Milk

Authors
Vasconcelos, H; Matias, A; Jorge, P; Saraiva, C; Mendes, J; Araújo, J; Dias, B; Santos, P; Almeida, JMMM; Coelho, LCC;

Publication
Chemistry Proceedings

Abstract
Over the years, the food industry’s concern to provide safe food that does not cause harm or illness to consumers has increased. The growing demand for the detection of compounds that can contaminate food is increasingly important. Hydrogen peroxide is frequently used as a substance to control the growth of microorganisms in milk, thus increasing its shelf life. Here, a strategy is presented for the detection of hydrogen peroxide as a milk adulterant, using a single shot membrane sensor. The lowest concentration measured with this technique was 0.002% w/w of H2O2 in semi-fat milk.

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