Abstract
The National Emission Ceilings Directive 2001/81/CE (NEC Directive) was adopted in the European Community in 2001 and went through a revision process in 2005. One of its main objectives is to improve the protection of the environment and human health against the risks of adverse effects from ground-level ozone, moving towards the long-term objective of not exceeding critical levels proved to effectively protect the populations and ecosystems. Considering such objectives, national emission ceilings were established imposing the years 2010 and 2020 as benchmarks. Ten years later, what was the effectiveness of this Directive concerning the control of tropospheric ozone levels in Portugal? In order to answer the previous question, annual ozone precursors' emissions (NOx, NMVOC) and annual atmospheric concentrations (NOx and O-3) were analyzed between 1990 and 2011. The background concentrations were assessed in each environment type of air quality station (urban, suburban and rural) through their annual mean ozone concentration and the hourly information threshold exceedances (episodic peak levels). To evaluate the statistical differences in the inter-annual episodic peak levels, a Peak Ozone Index (POIx) was defined and calculated. The results show that, despite the achievement on the emissions NEC Directive goals, associated to the reduction of ozone precursors' emissions, and the decrease of ozone episodic peak levels, the mean tropospheric ozone concentrations significantly increased between 2003 and 2007 (p < 0.05) although the number of exceedances to the information threshold (180 mu g m(-3)) has decreased. During the period of 1990-2000, before the implementation of the NEC Directive, the mean ozone values were 25% lower in rural stations, 26% in urban stations and 12% in suburban stations, demonstrating that the NEC policy based on NOx and NMVOCs emissions reduction does not lead to an effective overall reduction of ozone concentrations considering the reduction on these pollutants independently. Indeed, the mesoscale ozone production and/or the long range advection may play also an important role as the analysis of Mace Head ozone concentrations suggests. Above all, and due to its non-linear interactions in the ozone chemical balance, the NEC directive should impose emissions' reduction respecting the NOx/NMVOC ratio instead of consider it as a mere guideline value. The mesoscale photochemical ozone production should be carefully analyzed under the new policies, namely in coastal countries like Portugal where the mesoscale circulations play a crucial role in this type of phenomena.

Abstract
Artificial Neural Networks (ANN) have been essentially used as regression models to predict the concentration of one or more pollutants usually requiring information collected from air quality stations. In this work we consider a Multilayer Perceptron (MLP) with one hidden layer as a classifier of the impact of air quality on human health, using only traffic and meteorological data as inputs. Our data was obtained from a specific urban area and constitutes a 2-class problem: above or below the legal limits of specific pollutant concentrations. The results show that an MLP with 40 to 50 hidden neurons and trained with the cross-entropy cost function, is able to achieve a mean error around 11%, meaning that air quality impacts can be predicted with good accuracy using only traffic and meteorological data. The use of an ANN without air quality inputs constitutes a significant achievement because governments may therefore minimize the use of such expensive stations.

Abstract
Innovative traffic management measures are needed to reduce transportation-related emissions. While in Europe, road lane management has focused mainly on introduction of bus lanes, the conversion to High Occupancy Vehicles (HOV) and eco-lanes (lanes dedicated to vehicles running on alternative fuels) has not been studied comprehensively. The objectives of this research are to: (1) Develop an integrated microscopic modeling platform calibrated with real world data to assess both traffic and emissions impacts of future Traffic Management Strategies (TMS) in an urban area; (2) Evaluate the introduction of HOV/eco-lanes in three different types of roads, freeway, arterial and urban routes, in an European medium-sized city and its effects in terms of emissions and traffic performance. The methodology consists of three distinct phases: (a) Traffic and road inventory data collection; (b) Traffic and emissions simulation using an integrated platform of microscopic simulation; and (c) Evaluation of scenarios. For the baseline scenario, the statistical analysis shows valid results. The results show that HOV and eco-lanes in a medium European city are feasible, and when the Average Occupancy of Vehicles (AOV) increases, on freeways, the majority of vehicles can reduce their travel time (2%) with a positive impact in terms of total emissions (-38% NOx, -39% HC, -43% CO and -37% CO2). On urban and arterial corridors, the reduction in emissions could be achieved only if the AOV increases from 1.50 to 1.70 passengers/vehicle. Total emissions of the corridor with an AOV of 1.70 passengers/vehicle can be reduced up to 35-36% for the urban route while the values can be reduced by 36-39% for the arterial road. With the introduction of Hybrid Electric Vehicles (HEV) and Electric Vehicles (EV) it is possible to reduce emissions, although the introduction of eco-lanes did not show significant reductions in emissions. When both policies are simulated together, an emissions improvement is observed for the arterial route and for two of the scenarios.

Abstract
The aim of this research is the implementation of a GPS-based modelling approach for improving the characterization of vehicle speed spatial variation within urban areas, and a comparison of the resulting emissions with a widely used approach to emission inventory compiling. The ultimate goal of this study is to evaluate and understand the importance of activity data for improving the road transport emission inventory in urban areas. For this purpose, three numerical tools, namely, (i) the microsimulation traffic model (VISSIM); (ii) the mesoscopic emissions model (TREM); and (iii) the air quality model (URBAIR), were linked and applied to a mediumsized European city (Aveiro, Portugal). As an alternative, traffic emissions based on a widely used approach are calculated by assuming a vehicle speed value according to driving mode. The detailed GPS-based modelling approach results in lower total road traffic emissions for the urban area (7.9, 5.4, 4.6 and 3.2% of the total PM10, NOx, CO and VOC daily emissions, respectively). Moreover, an important variation of emissions was observed for all pollutants when analysing the magnitude of the 5th and 95th percentile emission values for the entire urban area, ranging from -15 to 49% for CO, -14 to 31% for VOC, -19 to 46% for NOx and -22 to 52% for PM10. The proposed GPS-based approach reveals the benefits of addressing the spatial and temporal variability of the vehicle speed within urban areas in comparison with vehicle speed data aggregated by a driving mode, demonstrating its usefulness in quantifying and reducing the uncertainty of road transport inventories.

Abstract
Nowadays, several methods to promote a more sustainable distribution of traffic flows are available. In response to rising energy costs and increased environmental concerns, eco-friendly route choices can be provided individually by means of smart navigation tools that allow several vehicle routing options designed to minimize air pollutant emissions and fuel consumption. Simultaneously, the use of intelligent road pricing systems and the use of variable message signs can change the route choice process of drivers (and thus network equilibrium), by varying the perceived attributes of competing routes. However, so far too little attention has been paid to the fact that the ecofriendliness of various routes may change, depending on vehicle characteristics which may cause problems on the efficiency of these systems. This issue has been empirically addressed in this research, using a database of more than 13,330 km of GPS data in six different Origin-Destination (OD) pairs and 9 different routes. Simultaneously, two different approaches for estimating (CO2, HC, CO, NOx) emissions were tested: a) second-by-second vehicle dynamics, using the Vehicle Specific Power (VSP) instantaneous model; and b) route average speed using the EMEP/PEA methodology. The results show that depending on the characteristics of the routes associated with a certain OD pair, the eco-friendly route may differ according to the vehicle model and the emissions estimation method. Innovative approaches to provide accurate emissions and eco-routing information are needed.

Abstract
Recently, roundabouts in a series have been installed along corridors to enhance road safety. However, the benefits of this traffic-calming technique on traffic performance and pollutant emissions compared with other forms of intersections, such as traffic lights and stop-controlled solutions, are not properly known. This study used a microscopic approach to evaluate the effects of a corridor with four roundabouts on traffic performance and emissions, in comparison with traffic lights and stop-controlled solutions. Average travel time and number of vehicle stops were used as measures of traffic performance; carbon dioxide, monoxide carbon, nitrogen oxides, hydrocarbons, and particulate matter were used to quantify emissions. The traffic and emissions performance of each solution was evaluated on three levels: (a) arterial, (b) intersection, and (c) morning peak versus evening peak periods. It was found that, regardless of the time period, traffic lights in corridors at the arterial level produced higher total emissions (> 6%), while stop-controlled intersections produced lower emissions (approximate to 12%) compared with roundabouts, mainly because of unbalanced traffic flows between main and minor roads. The results for traffic performance showed advantages in implementing roundabouts when the main concern was the number of vehicle stops. At the intersection level, an emissions improvement (between 2% and 14%) was observed at traffic lights on four-leg intersections.