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Publications

Publications by Marcos Martins

2017

Energy Harvesting to Supply Moored Oceanographic Monitoring Stations

Authors
Faria, CL; Martins, MS; Lima, R; Goncalves, LM;

Publication
OCEANS 2017 - ABERDEEN

Abstract
This work aims to study a new energy harvesting device to be anchored on the ocean floor and convert any type of currents, tides or oscillation movement into electrical energy using linear electromagnetic generators. The final application is to supply energy to a set of moored monitoring sensors that collects data and allowing the system to be energetically autonomous. The proposed setup is a spherical buoy with no external moving parts, to be more biofouling proof. The maximum output power measured for a 4 Hz movement was 9.9 mW with only one linear electromagnetic generator.

2018

Energy harvesting to increase the autonomy of moored oceanographic monitoring stations

Authors
Faria C.L.; Goncalves L.M.; Martins M.S.; Lima R.;

Publication
2018 OCEANS - MTS/IEEE Kobe Techno-Oceans, OCEANS - Kobe 2018

Abstract
Device to increase energy autonomy of moored oceanographic monitoring stations. Oscillations and currents through the sea or river are used to produce energy when the whole system is submerged to a depth between 3 to 10 meters. In order to have an inexpensive system, a buoy containing a Linear Electromagnetic Generator (LEG), is fabricated in a 3D printer, using PLA (polylactic acid) filament. Inside of the buoy, one cylinder shaped LEG (98mm length and 25mm of diameter) produces a maximum output power of 20 mW with a 4 Hz movement. To increase power output in larger systems, more LEGs can be added.

2019

Optical device for in situ monitoring of suspended particulate matter and organic/inorganic distinguish

Authors
Matos, T; Faria, CL; Martins, M; Henriques, R; Goncalves, L;

Publication
OCEANS 2019 - Marseille, OCEANS Marseille 2019

Abstract
A cost-effective (less than 20€) and low-power device is present for in situ continuous monitoring of suspended sediments (SPM) concentration in estuarine and coastal areas. The sensor uses nephelometric technique for SPM values less than 20g/L and backscatter technique for higher ones. A transmitted infrared (IR) and ultraviolet (UV) channels are used to perform the distinguish of inorganic from organic matter in the suspended particles. It is explained the design and built of the sensor as its calibration and preparation for in field tests. The sensor was deployed for one week in a small dock in the estuarine zone of Cavado river (Esposende, Portugal) where is analyzed the SPM and organic/inorganic matter change with the tidal cycles.

2021

A cost-effective oxygen probe manufactured by simple fabrication processes

Authors
Penso, C; Rocha, J; Martins, M; Sousa, P; Pinto, V; Minas, G; Silva, MM; Goncalves, L;

Publication
OCEANS 2021: San Diego – Porto

Abstract

2021

Dielectric spectroscopy of melt-extruded polypropylene and as-grown carbon nanofiber composites

Authors
Paleo, AJ; Samir, Z; Aribou, N; Nioua, Y; Martins, MS; Cerqueira, MF; Moreira, JA; Achour, ME;

Publication
European Physical Journal E

Abstract
Abstract: In this work, different weight contents of as-grown carbon nanofibers (CNFs), produced by chemical vapor deposition, were melt-extruded with polypropylene (PP) and their morphologic, structure and dielectric properties examined. The morphologic analysis reveals that the CNFs are randomly distributed in the form of agglomerates within the PP matrix, whereas the structural results depicted by Raman analysis suggest that the degree of disorder of the as-received CNFs was not affected in the PP/CNF composites. The AC conductivity of PP/CNF composites at room temperature evidenced an insulator–conductor transition in the vicinity of 2 wt.%, corresponding to a remarkable rise of the dielectric permittivity up to ~ 12 at 400 Hz, with respect to the neat PP (~ 2.5). Accordingly, the AC conductivity and dielectric permittivity of PP/CNF 2 wt.% composites were evaluated by using power laws and discussed in the framework of the intercluster polarization model. Finally, the complex impedance and Nyquist plots of the PP/CNF composites are analyzed by using equivalent circuit models, consisting of a constant phase element (CPE). The analysis gathered in here aims at contributing to the better understanding of the enhanced dielectric properties of low-conducting polymer composites filled with carbon nanofibers. Graphic abstract: [Figure not available: see fulltext.]. © 2021, The Author(s), under exclusive licence to EDP Sciences, SIF and Springer-Verlag GmbH Germany, part of Springer Nature.

2021

PtOEP-PDMS-Based Optical Oxygen Sensor

Authors
Penso, CM; Rocha, JL; Martins, MS; Sousa, PJ; Pinto, VC; Minas, G; Silva, MM; Goncalves, LM;

Publication
SENSORS

Abstract
The advanced and widespread use of microfluidic devices, which are usually fabricated in polydimethylsiloxane (PDMS), requires the integration of many sensors, always compatible with microfluidic fabrication processes. Moreover, current limitations of the existing optical and electrochemical oxygen sensors regarding long-term stability due to sensor degradation, biofouling, fabrication processes and cost have led to the development of new approaches. Thus, this manuscript reports the development, fabrication and characterization of a low-cost and highly sensitive dissolved oxygen optical sensor based on a membrane of PDMS doped with platinum octaethylporphyrin (PtOEP) film, fabricated using standard microfluidic materials and processes. The excellent mechanical and chemical properties (high permeability to oxygen, anti-biofouling characteristics) of PDMS result in membranes with superior sensitivity compared with other matrix materials. The wide use of PtOEP in sensing applications, due to its advantage of being easily synthesized using microtechnologies, its strong phosphorescence at room temperature with a quantum yield close to 50%, its excellent Strokes Shift as well as its relatively long lifetime (75 mu s), provide the suitable conditions for the development of a miniaturized luminescence optical oxygen sensor allowing long-term applications. The influence of the PDMS film thickness (0.1-2.5 mm) and the PtOEP concentration (363, 545, 727 ppm) in luminescent properties are presented. This enables to achieve low detection levels in a gas media range from 0.5% up to 20%, and in liquid media from 0.5 mg/L up to 3.3 mg/L at 1 atm, 25 degrees C. As a result, we propose a simple and cost-effective system based on a LED membrane photodiode system to detect low oxygen concentrations for in situ applications.

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