Abstract
As humanity progresses and globalization advances, humanized environment and associated systems increase in complexity and size. In earth systems, oceans represent an essential element of equalization and normal functioning. Ocean-atmospheric interactions are nowadays believed to be at the heart of all earth vital signs and climatic behaviours, and therefore are essential to accurate monitoring and understanding of earth systems. The work presented is a preliminary result of the K2D- Knowledge and Data from the Deep to Space, project which addresses the challenge of creating underwater network nodes to provide power and communication to land through the submarine fiber optic cable repeaters. The N2ODE system will consist of a set of subsystems that will allow continuous monitoring and interaction with fixed and mobile underwater devices.

Abstract
Long-term and reliable marine ecosystems monitoring is essential to address current environmental issues, including climate change and biodiversity threats. The existing oceans monitoring systems show clear data gaps, particularly when considering characteristics such as depth coverage or measured variables in deep and open seas. Over the last decades, the number of fixed and mobile platforms for in situ ocean data acquisition has increased significantly, covering all oceans' regions. However, these are largely dependent on satellite communications for data transmission, as well as on research cruises or opportunistic ship surveys, generally presenting a lag between data acquisition and availability. In this context, the creation of a widely distributed network of SMART cables (Science Monitoring And Reliable Telecommunications) - sensors attached to submarine telecommunication cables - appears as a promising solution to fill in the current ocean data gaps and ensure unprecedented oceans health continuous monitoring. The K2D (Knowledge and Data from the Deep to Space) project proposes the development of a persistent oceans monitoring network based on the use of telecommunications cables and Autonomous Underwater Vehicles (AUVs). The approach proposed includes several modules for navigation, communication and energy management, that enable the cost-effective gathering of extensive oceans data. These include physical, chemical, and biological variables, both registered with bottom fixed stations and AUVs operating in the water column. The data that can be gathered have multiple potential applications, including oceans health continuous monitoring and the enhancement of existing ocean models. The latter, in combination with geoinformatics and Artificial Intelligence, can create a continuum from the deep sea to near space, by integrating underwater remote sensing and satellite information to describe Earth systems in a holistic manner.

Abstract
Robust wireless communication networks are a cornerstone of the modern world, allowing data to be transferred quickly and reliably. Establishing such a network at sea, a Maritime Internet of Things (MIoT), would enhance services related to safety and security at sea, environmental protection, and research. However, given the remote and harsh nature of the sea, installing robust wireless communication networks with adequate data rates and low cost is a difficult endeavor. This paper reviews recent MIoT systems developed and deployed by researchers and engineers over the past few years. It contains an analysis of short-range and long-range over-the-air radio-frequency wireless communication protocols and the synergy between these two in the pursuit of an MIoT. The goal of this paper is to serve as a go-to guide for engineers and researchers that need to implement a wireless sensor network at sea. The selection criterion for the papers included in this review was that the implemented wireless communication networks were tested in a real-world scenario.

Abstract
A linear electromagnetic energy harvesting device for underwater applications, fabricated with a simple manufacturing process, was developed to operate with movement frequencies from 0.1 to 0.4 Hz. The generator has two coils, and the effect of the combination of the two coils was investigated. The experimental study has shown that the energy capture system was able to supply energy to several ocean sensors, producing 7.77 mJ per second with wave movements at 0.4 Hz. This study shows that this energy is enough to restore the energy used by the battery or the capacitor and continue supplying energy to the sensors used in the experimental work. For an ocean wave frequency of 0.4 Hz, the generator can supply power to 8 sensors or 48 sensors, depending on the energy consumed and its optimization.

Abstract
Laboratories and industries that handle chemicals are ubiquitously prone to leakages. These may occur in storage rooms, cabinets or even in temporary locations, such as workbenches and shelves. A relevant number of these chemicals are corrosive, thus commercial products already exist to prevent material damage and injuries. One strategy consists of the use of absorbing mats, where few display neutralizing properties, and even less a controlled neutralization. Nevertheless, to the authors' knowledge, the commercially available neutralizing mats are solely dedicated to neutralizing acid or alkali solutions, never both. Therefore, this work describes the development and proof of a completely novel concept, where a dual component active mat (DCAM) is able to perform a controlled simultaneous neutralization of acid and alkali leakages by using microencapsulated active components. Moreover, its active components comprise food-grade ingredients, embedded in nonwoven polypropylene. The acid neutralizing mats contain sodium carbonate (Na2CO3) encapsulated in sodium alginate microcapsules (MC-ASC). Alkali neutralizing mats possess commercial encapsulated citric acid in hydrogenated palm oil (MIRCAP CT 85-H). A DCAM encompasses both MC-ASC and MIRCAP CT 85-H and was able to neutralize solutions up to 10% (v/v) of hydrochloric acid (HCl) and sodium hydroxide (NaOH). The efficacy of the neutralization was assessed by direct titration and using pH strip measurement tests to simulate the leakages. Due to the complexity of neutralization efficacy evaluation based solely on pH value, a thorough conductivity study was performed. DCAM reduced the conductivity of HCl and NaOH (1% and 2% (v/v)) in over 70%. The composites were characterized by scanning electron microscopy (SEM), differential calorimetry (DSC) and thermogravimetric analysis (TGA). The size of MC-ASC microcapsules ranged from 2 mu m to 8 mu m. Finally, all mat components displayed thermal stability above 150 degrees C.

Abstract
A piston type projector using the PVDF piezoelectric polymer was developed for operating in underwater environment, below 100 kHz. For those frequencies PZT piezoelectric ceramic is usually a preferable choice and PVDF is only considered for frequencies above a few hundreds of kHz. This paper will show that efficient underwater acoustic projectors for frequencies below 100 kHz can be implemented regarding an appropriate impedance adapter is being used. The developed project presents a calibrated transmitting voltage response (TVR) of approximately 166, 160 and 175 dB at 40, 50 and 75 kHz, respectively. The PVDF TVR values are compatible with the PZT projectors available on market with the advantage of having a larger bandwidth than most PZT projectors. To the authors knowledge this is the first time that a PVDF projector attain such characteristics. Although theoretically the PVDF projector bandwidth is larger than 40 to 80 kHz, in practice it was observed that only between those frequencies the project presents a stable operation for the transmission of long-term signals.