2021
Authors
Mendes, JP; Coelho, LCC; Pereira, VP; Azenha, MA; Jorge, PAS; Pereira, CM;
Publication
Chemistry Proceedings
Abstract
2021
Authors
Vasconcelos, H; Matias, A; Jorge, P; Saraiva, C; Mendes, J; Araújo, J; Dias, B; Santos, P; Almeida, JMMM; Coelho, LCC;
Publication
Chemistry Proceedings
Abstract
2021
Authors
da Silva, PM; Coelho, LCC; Almeida, JMMMD;
Publication
CHEMOSENSORS
Abstract
Reinforced concrete structures are an essential part of our modern society, and monitoring their structural health is of paramount importance. Early detection of decay allows for the reduction of repair costs and, more importantly, the prevention of catastrophic failure. For this purpose, a single fiber reflectance spectrometer was embedded in cement paste samples for the monitoring of water at the fiber tip through its sensitivity to changes in the refractive index. It monitored the curing of samples with different water-to-cement ratios (w/c), between 0.45 and 0.60, measuring the water exhaust during the hardening of the cement paste. It also measured the capillary coefficient from cement paste samples of 0.50, 0.55 and 0.60 w/c: 0.668 & PLUSMN; 0.002 mm/& RADIC;h, 1.771 & PLUSMN; 0.052 mm/& RADIC;h and 6.360 & PLUSMN; 0.269 mm/& RADIC;h, respectively. The capillary coefficient values agree with gravimetric measurements of sorptivity and are further confirmed through porosity measurements made with a scanning electron microscope. Thus, single fiber reflectance spectroscopy can be a gateway to inexpensively measure the entire life cycle of cement, from its curing until its eventual decay, assessing, in situ, its durability through the capillary coefficient.
2021
Authors
Dias, B; Mendes, JP; de Almeida, JMMM; Coelho, LCC;
Publication
Chemistry Proceedings
Abstract
2022
Authors
Dias, B; Carvalho, J; Mendes, JP; Almeida, JMMM; Coelho, LCC;
Publication
POLYMERS
Abstract
Relative humidity (RH) monitorization is of extreme importance on scientific and industrial applications, and optical fiber sensors (OFS) may provide adequate solutions. Typically, these kinds of sensors depend on the usage of humidity responsive polymers, thus creating the need for the characterization of the optical and expansion properties of these materials. Four different polymers, namely poly(vinyl alcohol), poly(ethylene glycol), Hydromed (TM) D4 and microbiology agar were characterized and tested using two types of optical sensors. First, optical fiber Fabry-Perot (FP) tips were made, which allow the dynamical measurement of the polymers' response to RH variations, in particular of refractive index, film thickness, and critical deliquescence RH. Using both FP tips and Long-Period fiber gratings, the polymers were then tested as RH sensors, allowing a comparison between the different polymers and the different OFS. For the case of the FP sensors, the PEG tips displayed excellent sensitivity above 80%RH, outperforming the other polymers. In the case of LPFGs, the 10% (wt/wt) PVA one displayed excellent sensitivity in a larger working range (60 to 100%RH), showing a valid alternative to lower RH environment sensing.
2021
Authors
Silva, AF; Löfkvist, K; Gilbertsson, M; Os, EV; Franken, G; Balendonck, J; Pinho, TM; Boaventura-Cunha, J; Coelho, L; Jorge, P; Martins, RC;
Publication
Chemistry Proceedings
Abstract
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