Abstract
This work reports the theoretical investigation of optical fiber surface plasmon resonance sensors incorporating an internal metallic layer of silver covered with an oxide layer. This research is supported by the application of an effective analytical model combining geometrical optics with the transfer matrix theory for stratified optical media. Different oxide materials like titanium dioxide, silicon dioxide, and aluminum oxide are considered aiming to achieve increased/enhanced sensitivity to refractive index variations of the external medium, particularly when addressing phase interrogation. It is shown that the combination of a 50-nm thickness silver inner layer with a dielectric titanium oxide layer of a specific thickness enables high-performance phase sensitivity reading and is compatible with tailoring the sensor working region to the third telecommunication wavelength window around 1550 nm.

Abstract
The wine sector is a billion euro business and therefore subjected to multiple attempts of fraudulent practices. This requires the development of rapid and reliable methods to detect such situations. Several methodologies have been developed based on the chemical profiles of the wines, but they are limited due to the environmental conditions that cannot be controlled. The use of DNA-based detection systems are an emergent research field that have been extended to a wide variety of food products and are still the most reliable methods for varietal identification. However these methods are not suitable for geographical determination. Soil related fingerprints have a primary role considering that there is a relationship between the elemental composition of wine and the composition of the provenance soil. WineBioCode is a project aiming to define the best strategy for wine authenticity based on a multidisciplinary approach. Two DNA-based strategies have been developed based on Real-time PCR and a label free optical biosensor platform. Both platforms enabled successful identification of specific DNA-targets when applied to Vitis vinifera L., and can be applied throughout the grape-wine chain. The methods are complementary and can be used in different situations, according to the requirements. The geographical evaluation has been assessed by the strontium 875r1865r isotope ratio determination involving soil evaluation in the vineyards followed by its assay in the wine samples. The results are being integrated in order to establish the best procedure to be undertaken for wine fingerprinting, including varietal composition and geographical origin, therefore fulfilling the requirements of the geographical denominations in wine certification.

Abstract
The detection of volatile organic compounds is accomplished with a sensing device based on a long period fiber grating (LPFG) coated with a zinc oxide (ZnO) thin layer with self-temperature compensation. The ZnO coating structure was produced onto the cladding of the fiber by thermal oxidation of a metallic Zn thin film. The morphological characterization of ZnO thin films, grown at the same time on silicon substrates, was performed using X-ray diffraction, X-ray Photoelectron Spectroscopy and Scanning Electron Microscope which shows very good agreement. LPFGs with 290 nm thick ZnO coating were fabricated and characterized for the detection of ethanol and hexane in vapor phase. For ethanol a sensitivity of 0.99 nm / g.m(-3) was achieved when using the wavelength shift interrogation mode, while for hexane a much lower sensitivity of 0.003 nm / g.m(-3) was measured, indicating a semi-selectivity of the sensor with a spectral resolution better than 3.2 g.m(-3).

Abstract
Many optical systems based on surface plasmon resonance (SPR) have been developed for working as refractometers, chemical sensors or even for measuring the thickness of metal and dielectric thin films. Sensors based on SPR present very high sensitivity to refractive index (RI) variations when compared to the traditional RI sensors. However, these kinds of systems are usually large, expensive and therefore cannot be used for remote sensing. Optical fibre sensors based on SPR are usually implemented using multimode optical fibres cope with the requirements for remote sensing. In this section a new type of SPR sensor based in a single mode fibre (SMF) is proposed. A section of the SMF was chemically etched by emersion in a 48 % hydrofluoric acid solution, resulting in a tapering effect, with the cladding removing while the core is kept intact. Simulation results are in good agreement with the experimental spectral resonance dip attained around 1550 nm. Sensitivities of 3800 and 5100 nm/RIU were achieved for the reflection and for the transmission modes, respectively, for RI in the 1.33 to 1.37 range.

Abstract
Long period fiber gratings (LPFGs) were over coated with iron (Fe) and subjected to oxidation in air and in solutions of water containing different sodium chloride (NaCl) concentrations. The formation of iron oxides and hydroxides was monitored in real time by following the features of the gratings attenuation band. Preliminary results show that Fe coated LPFGs can be used as sensors for early warning of corrosion in offshore and in coastal projects where metal structures made of iron alloys are in contact with sea or brackish water.

Abstract
It is reported a new optical sensing system, based on long period fiber gratings (LPFGs) coated with cuprous oxide (Cu2O), for the quantification of ethanol concentration in ethanol-gasoline mixtures. The detection principle is based on the spectral features dependence of the Cu2O coated LPFGs on the refractive index of the surrounding medium. The chemical constitution of the ethanol-gasoline samples was obtained by gas chromatography mass spectrometry (GC) and GC thermal conductivity detection. Two different modes of operation are presented, wavelength shift and optical power shift mode of operation, with good linear relations between ethanol concentration and the corresponding spectral features of the LPFGs, R-2 = 0.999 and 0.996, respectively. In the range of ethanol concentration up to 30% v/v, the sensitivities were 0.76 +/- 0.01 nm/% v/v and 0.125 +/- 0.003 dB/% v/v with resolutions of 0.21% v/v and 0.73% v/v and limits of detection of 1.63% v/v and 2.10% v/v, for the for the same operation modes, respectively.