2023
Autores
Perez-Herrera, RA; Diaz, H; Soares, L; Novais, S; Lopez-Amo, M; Silva, S; Frazão, O;
Publicação
EPJ Web of Conferences
Abstract
2022
Autores
Cardoso, MP; Silva, AO; Romeiro, AF; Giraldi, MTR; Costa, JCWA; Santos, JL; Baptista, JM; Guerreiro, A;
Publicação
APPLIED SCIENCES-BASEL
Abstract
Subwavelength cells of metallic nanorods arrayed in a dielectric background, termed "metamaterials", present bulk properties that are useful to control and manipulate surface plasmon resonances. Such feature finds tremendous potential in providing a broad manifold of applications for plasmonic optical sensors. In this paper, we propose a surface-plasmon-resonance-based sensor with spectral response tunable by the volume fraction of silver present in a metamaterial layer deposited on a D-shaped photonic crystal fiber. Using computational simulations, we show that sensitivity and resolution can be hugely altered by changing the amount of constituents in the metamaterial, with no further modifications in the structure of the sensor. Moreover, the designed sensor can also be applied to label the average volume fraction of silver in the metamaterial layer and then to estimate its effective constitutive parameters.
2022
Autores
Cardoso, VHR; Caldas, P; Giraldi, MTR; Fernandes, CS; Frazao, O; Costa, JCWA; Santos, JL;
Publicação
SENSORS
Abstract
In many areas, the analysis of a cylindrical structure is necessary, and a form to analyze it is by evaluating the diameter changes. Some areas can be cited: pipelines for oil or gas distribution and radial growth of trees whose diameter changes are directly related to irrigation and the radial expansion since it depends on the water soil deficit. For some species, these radial variations can change in around 5 mm. This paper proposes and experimentally investigates a sensor based on a core diameter mismatch technique for diameter changes measurement. The sensor structure is a combination of a cylindrical piece developed using a 3D printer and a Mach-Zehnder interferometer. The pieces were developed to assist in monitoring the diameter variation. It is formed by splicing an uncoated short section of MMF (Multimode Fiber) between two standard SMFs (Singlemode Fibers) called SMF-MMF-SMF (SMS), where the MMF length is 15 mm. The work is divided into two main parts. Firstly, the sensor was fixed at two points on the first developed piece, and the diameter reduction caused dips or peaks shift of the transmittance spectrum due to curvature and strain influence. The fixation point (FP) distances used are: 5 mm, 10 mm, and 15 mm. Finally, the setup with the best sensitivity was chosen, from first results, to develop another test with an optimization. This optimization is performed in the printed piece where two supports are created so that only the strain influences the sensor. The results showed good sensitivity, reasonable dynamic range, and easy setup reproduction. Therefore, the sensor could be used for diameter variation measurement for proposed applications.
2022
Autores
Cardoso, VHR; Caldas, P; Giraldi, MTR; Frazao, O; Costa, JCWA; Santos, JL;
Publicação
SENSORS
Abstract
An optical strain gauge based on a balloon-like interferometer structure formed by a bent standard single-mode fiber combined with a 3D printer piece has been presented and demonstrated, which can be used to measure displacement. The interferometer has a simple and compact size, easy fabrication, low cost, and is repeatable. The sensor is based on the interference between the core and cladding modes. This is caused by the fiber's curvature because when light propagates through the curved balloon-shaped interferometer region, a portion of it will be released from the core limitation and coupled to the cladding. The balloon has an axial displacement as a result of how the artwork was constructed. The sensor head is sandwiched between two cantilevers such that when there is a displacement, the dimension associated with the micro bend is altered. The sensor response as a function of displacement can be determined using wavelength shift or intensity change interrogation techniques. Therefore, this optical strain gauge is a good option for applications where structure displacement needs to be examined. The sensor presents a sensitivity of 55.014 nm for displacement measurements ranging from 0 to 10 mm and a strain sensitivity of 500.13 pm/mu epsilon.
2022
Autores
Martins, RC; Barroso, TG; Jorge, P; Cunha, M; Santos, F;
Publicação
COMPUTERS AND ELECTRONICS IN AGRICULTURE
Abstract
Analytical grade 'in vivo' plant metabolic quantification using spectroscopy is a key enabling technology for precision agriculture.Current methods such as PLS, ANN and LS-SVM are non-optimal for resolving spectral interference and matrix effects to provide similar results to the analytical chemistry laboratory. This research presents a new self-learning artificial intelligence (SL-AI) method based on the search of covariance modes. These isolate the different modes of interference present in spectral data, allowing the consistent quantification of constituents. A review of the state-of-the-art methods with the figures of merit mean absolute standard error percentage (MASEP) and Pearson correlation coefficient (R) is presented for comparison and discussion. 707 grapes were quantified for glucose, fructose, malic and tartaric acids in five wine-making and one table grape varieties, and used to benchmark the new method against the state-of-the-art methodologies: partial least squares, local partial least squares, artificial neural networks and least squares support vector machines. SL-AI provides consistent quantifications, whereas previous methods exhibit data-driven performance dependence. Pearson correlations of 0.93 to 0.99 and MASEP of 3.70% to 7.33% were obtained with the new methodology. Local partial least squares, the method with the best benchmarks from literature, achieved correlations of 0.81 to 0.94 and MASEP of 8.00% to 13.4%. The covariance mode isolates a particular interference, providing a direct relationship between spectral inference and constituent concentrations, consistent with the Beer-Lambert law. Such quantifies non-dominant absorbance constituents (e.g. sugars and acids), which is a significant step towards 'in vivo' plant physiology-based precision agriculture.
2022
Autores
Arcadio, F; Seggio, M; Del Prete, D; Buonanno, G; Mendes, J; Coelho, LCC; Jorge, PAS; Zeni, L; Bossi, AM; Cennamo, N;
Publicação
NANOMATERIALS
Abstract
Plasmonic bio/chemical sensing based on optical fibers combined with molecularly imprinted nanoparticles (nanoMIPs), which are polymeric receptors prepared by a template-assisted synthesis, has been demonstrated as a powerful method to attain ultra-low detection limits, particularly when exploiting soft nanoMIPs, which are known to deform upon analyte binding. This work presents the development of a surface plasmon resonance (SPR) sensor in silica light-diffusing fibers (LDFs) functionalized with a specific nanoMIP receptor, entailed for the recognition of the protein human serum transferrin (HTR). Despite their great versatility, to date only SPR-LFDs functionalized with antibodies have been reported. Here, the innovative combination of an SPR-LFD platform and nanoMIPs led to the development of a sensor with an ultra-low limit of detection (LOD), equal to about 4 fM, and selective for its target analyte HTR. It is worth noting that the SPR-LDF-nanoMIP sensor was mounted within a specially designed 3D-printed holder yielding a measurement cell suitable for a rapid and reliable setup, and easy for the scaling up of the measurements. Moreover, the fabrication process to realize the SPR platform is minimal, requiring only a metal deposition step.
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