Susana Alexandra Barbosa

Abstract
Palaeoclimate time series, reflecting the state of Earth's climate in the distant past, occasionally display very large and rapid shifts showing abrupt climate variability. The identification and characterisation of these abrupt transitions in palaeoclimate records is of particular interest as this allows for understanding of millennial climate variability and the identification of potential tipping points in the context of current climate change. Methods that are able to characterise these events in an objective and automatic way, in a single time series, or across two proxy records are therefore of particular interest. In our study the matrix profile approach is used to describe Dansgaard-Oeschger (DO) events, abrupt warmings detected in the Greenland ice core, and Northern Hemisphere marine and continental records. The results indicate that canonical events DO-19 and DO-20, occurring at around 72 and 76 ka, are the most similar events over the past 110 000 years. These transitions are characterised by matching transitions corresponding to events DO-1, DO-8, and DO-12. They are abrupt, resulting in a rapid shift to warmer conditions, followed by a gradual return to cold conditions. The joint analysis of the delta 18O and Ca2+ time series indicates that the transition corresponding to the DO-19 event is the most similar event across the two time series.

Abstract
Greenland ice core records display abrupt transitions, designated as Dansgaard-Oeschger (DO) events, characterised by episodes of rapid warming (typically decades) followed by a slower cooling. The identification of abrupt transitions is hindered by the typical low resolution and small size of paleoclimate records, and their significant temporal variability. Furthermore, the amplitude and duration of the DO events varies substantially along the last glacial period, which further hinders the objective identification of abrupt transitions from ice core records Automatic, purely data-driven methods, have the potential to foster the identification of abrupt transitions in palaeoclimate time series in an objective way, complementing the traditional identification of transitions by visual inspection of the time series.In this study we apply an algorithmic time series method, the Matrix Profile approach, to the analysis of the NGRIP Greenland ice core record, focusing on:- the ability of the method to retrieve in an automatic way abrupt transitions, by comparing the anomalies identified by the matrix profile method with the expert-based identification of DO events;- the characterisation of DO events, by classifying DO events in terms of shape and identifying events with similar warming/cooling temporal patternThe results for the NGRIP time series show that the matrix profile approach struggles to retrieve all the abrupt transitions that are identified by experts as DO events, the main limitation arising from the diversity in length of DO events and the method’s dependence on fixed-size sub-sequences within the time series. However, the matrix profile method is able to characterise the similarity of shape patterns between DO events in an objective and consistent way.

Abstract
Gamma radiation over the Atlantic Ocean was measured continuously from January to May 2020 by a NaI(Tl) detector installed on board the Portuguese navy's ship NRP Sagres. Enhancements in the gamma radiation values are identified automatically by an algorithm for detection of anomalies in mean and variance as well as by visual inspection. The anomalies are typically +50% above the background level and relatively rare events (similar to<10% of the days). All the detected anomalies are associated with simultaneous precipitation events, consistent with the wet deposition of scavenged radionuclides. The enhancements are detected in the open ocean even at large distances (+500 km) from the nearest coastline. Back trajectories reveal that half of these events are associated with air masses experiencing continental land influences, but the other half do not display evidence of recent land contact. The enhancements in gamma radiation very far from land and with no evidence of continental fetch from back trajectories are difficult to explain as resulting only from radionuclides with a terrestrial source such as radon and its progeny. Further investigation and additional measurements are needed to improve understanding on the sources of ambient radioactivity in the open ocean and assess whether gamma radiation in the marine environment is influenced not only by radionuclides of terrestrial origin, but also cosmogenic radionuclides, like Beryllium-7, formed in the upper atmosphere but with the ability to be transported downward and serve as a tracer of the aerosols to which it attaches. Plain Language Summary Radioactive elements such as the noble gas radon and those produced by its radioactive decay are naturally present in the environment and used as tracers of atmospheric transport and composition. In particular, the noble gas radon, being inert and of predominantly terrestrial origin, is used to identify pristine marine air masses with no land contamination. Precipitation over land typically brings radon from the atmosphere to the surface, enhancing gamma radiation on the ground, but such enhancements have not been identified before nor expected over the ocean due to the low amount of radon typical of marine air masses. Here we report, for the first time, gamma radiation enhancements associated with precipitation in the oceanic environment, using measurements performed over the Atlantic Ocean in a campaign onboard the Portuguese navy ship NRP Sagres.

Abstract
The ionosphere is a fundamental component of the Earth's atmosphere, impacting human activities such as communication transmissions, navigation systems, satellite functions, power network systems, and natural gas pipelines, even endangering human life or health. As technology moves forward, understanding the impact of the ionosphere on our daily lives becomes increasingly important. CubeSats are a promising way to increase understanding of this important atmospheric layer. This paper reviews the state of the art of CubeSat missions designed for ionospheric studies. Their main instrumentation payload and orbits are also analyzed from the point of view of their importance for the missions. It also focuses on the importance of data and metadata, and makes an approach to the aspects that need to be improved.

Abstract
&lt;p&gt;A novel ionisation detector, previously deployed on meteorological radiosonde flights, has demonstrated responsivity to X-rays and gamma radiation, and additionally, is thought to be sensitive to ionising radiation from cosmic rays. The PiN detector, composed of a 1x1x0.8 cm&lt;sup&gt;3 &lt;/sup&gt;CsI(Tl) microscintillator coupled to a PiN photodiode, was deployed on the NRP Sagres sailing vessel on a cruise in the Atlantic between Portugal and the Azores in 2021. The instrument can determine both the count rate and energy of incoming ionising radiation particles.&lt;/p&gt;&lt;p&gt;The instrument was operational during the voyage in November 2021 when a coronal mass ejection event induced a sudden decrease in the observed cosmic ray intensity, known as a Forbush decrease. We present data recorded by the ionisation detector during this period, to characterise the instrument&amp;#8217;s ability to detect cosmic ray events, and we compare the performance with neutron monitoring stations Oulu in Finland, and Dourbes in Belgium. As the PiN detector provides spectral and count rate data, it is possible to group events by their energy, and investigate the count rates of specific energy regimes. This approach is useful as many sources &amp;#8211; including high and low energy ionising radiation from cosmic rays &amp;#8211; contribute to the background energy spectrum. As a result, more meaningful comparisons and relationships can be established with the neutron monitoring stations.&lt;/p&gt;