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Publicações

Publicações por CAP

2025

Improving LIBS-based mineral identification with Raman imaging and spectral knowledge distillation

Autores
Lopes, T; Cavaco, R; Capela, D; Dias, F; Teixeira, J; Monteiro, CS; Lima, A; Guimaraes, D; Jorge, PAS; Silva, NA;

Publicação
TALANTA

Abstract
Combining data from different sensing modalities has been a promising research topic for building better and more reliable data-driven models. In particular, it is known that multimodal spectral imaging can improve the analytical capabilities of standalone spectroscopy techniques through fusion, hyphenation, or knowledge distillation techniques. In this manuscript, we focus on the latter, exploring how one can increase the performance of a Laser-induced Breakdown Spectroscopy system for mineral classification problems using additional spectral imaging techniques. Specifically, focusing on a scenario where Raman spectroscopy delivers accurate mineral classification performance, we show how to deploy a knowledge distillation pipeline where Raman spectroscopy may act as an autonomous supervisor for LIBS. For a case study concerning a challenging Li-bearing mineral identification of spodumene and petalite, our results demonstrate the advantages of this method in improving the performance of a single-technique system. LIBS trained with labels obtained by Raman presents an enhanced classification performance. Furthermore, leveraging the interpretability of the model deployed, the workflow opens opportunities for the deployment of assisted feature discovery pipelines, which may impact future academic and industrial applications.

2025

Advancing automated mineral identification through LIBS imaging for lithium-bearing mineral species

Autores
Capela, D; Lopes, T; Dias, F; Ferreira, MFS; Teixeira, J; Lima, A; Jorge, PAS; Silva, NA; Guimaraes, D;

Publicação
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY

Abstract
Mineral identification is a challenging task in geological sciences, which often implies multiple analyses of the physical and chemical properties of the samples for an accurate result. This task is particularly critical for the mining industry, where proper and fast mineral identification may translate into major efficiency and performance gains, such as in the case of the lithium mining industry. In this study, a mineral identification algorithm optimized for analyzing lithium-bearing samples using Laser-induced breakdown spectroscopy (LIBS) imaging, is put to the test with a set of representative samples. The algorithm incorporates advanced spectral processing techniques-baseline removal, Gaussian filtering, and data normalization-alongside unsupervised clustering to generate interpretable classification maps and auxiliary charts. These enhancements facilitate rapid and precise labelling of mineral compositions, significantly improving the interpretability and interactivity of the user interface. Extensive testing on diverse mineral samples with varying complexities confirmed the algorithm's robustness and broad applicability. Challenges related to sample granulometry and LIBS resolution were identified, suggesting future directions for optimizing system resolution to enhance classification accuracy in complex mineral matrices. The integration of this advanced algorithm with LIBS technology holds the potential to accelerate the mineral evaluation, paving the way for more efficient and sustainable mineral exploration.

2025

Normalized temperature sensitivity of fiber Bragg gratings inscribed under different conditions

Autores
Preizal, J; Cosme, M; Pota, M; Caldas, P; Araújo, FM; Oliveira, R; Nogueira, R; Rego, GM;

Publicação
29th International Conference on Optical Fiber Sensors

Abstract

2025

Semi-distributed optical fiber bending extensometer system for precision landslide monitoring based on OTDR

Autores
Santini, L; Caldas, P; Coelho, LC;

Publicação
29th International Conference on Optical Fiber Sensors

Abstract

2025

Flexible Wearable Optical Sensor Based on a Balloon-like Interferometer to Breathing Monitoring

Autores
Costa, N; Cardoso, HR; de Souza, FC; Caldas, P; Rocco Giraldi, MT; Frazão, O; Santos, L; Costa, CWA;

Publicação
Proceedings of SPIE - The International Society for Optical Engineering

Abstract
A flexible wearable sensor utilizing a balloon-shaped interferometer structure, created from a bent standard single-mode fiber and a 3D-printed piece, was introduced and shown for respiratory monitoring. The interferometer is a compact, cost-effective, and easily fabricated sensor. The fiber’s curvature causes interference between the core and cladding modes, which in turn results in the sensor operation. In the balloon-shaped curving section, light traversing the core partially escapes and interacts with the cladding. The preliminary results demonstrate an average displacement of 9.3 nm and the capability to evaluate breathing rate. © 2025 SPIE.

2025

Design and testing of a probe for diameter variation measurement based on fiber Bragg grating combined with additive manufacturing

Autores
Cardoso, VHR; Caldas, P; Giraldi, MTR; Fernandes, CS; Frazao, O; Costa, JCWA; Santos, JL;

Publicação
SENSORS AND ACTUATORS A-PHYSICAL

Abstract
A sensor based on the fiber Bragg grating (FBG) and additive manufacturing for diameter variation measurement is proposed and experimentally demonstrated in this work. Two designs were proposed: a FBG alone and a FBG in series with a spring. Three tests were developed for each design, and at the end, the statistical treatment was performed. The designs were fabricated using a 3D printer, and the FBG sensor is embedded. The results demonstrated that the structures proposed in this work can be used to monitor diameter variation, among other applications. The sensors, with and without spring in series, presented sensitivities of 0.0671 nm/mm and 0.5116 nm/mm, respectively, with a good linear response greater than 0.99.

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