2023
Autores
da Silva, PM; Coelho, LCC; de Almeida, JMMM;
Publicação
CHEMOSENSORS
Abstract
Water vapor sorption is a powerful tool for the analysis of cement paste, one of the most used substances by mankind. The monitoring of cementitious materials is fundamental for the improvement of infrastructure resilience, which has a deep impact on the economy, the environment, and on society. In this work, a multimode fiber was embedded in cement paste for real-time monitoring of cement paste water vapor sorption. Changes in the reflected light intensity due to the build-up of water in the cement paste's pores were exploited for this purpose. The sample was 7-day moist cured, and the relative humidity was controlled between 8.9% and 97.6%. Reflected light intensity was converted into a specific surface area of cement paste (133 m(2)/g) and thickness of water through the Brunauer-Emmett-Teller (BET) method and into a pore size distribution through the Barret-Joyner-Halenda (BJH) method. The results achieved through reflected light intensity agree with those found in the literature, validating the usage of this setup for the monitoring of water vapor sorption, breaking away from standard gravimetric measurements.
2023
Autores
Dos Santos, PSS; Mendes, JP; Dias, B; Perez-Juste, J; De Almeida, JMMM; Pastoriza-Santos, I; Coelho, LCC;
Publicação
SENSORS
Abstract
Biochemical-chemical sensing with plasmonic sensors is widely performed by tracking the responses of surface plasmonic resonance peaks to changes in the medium. Interestingly, consistent sensitivity and resolution improvements have been demonstrated for gold nanoparticles by analyzing other spectral features, such as spectral inflection points or peak curvatures. Nevertheless, such studies were only conducted on planar platforms and were restricted to gold nanoparticles. In this work, such methodologies are explored and expanded to plasmonic optical fibers. Thus, we study-experimentally and theoretically-the optical responses of optical fiber-doped gold or silver nanospheres and optical fibers coated with continuous gold or silver thin films. Both experimental and numerical results are analyzed with differentiation methods, using total variation regularization to effectively minimize noise amplification propagation. Consistent resolution improvements of up to 2.2x for both types of plasmonic fibers are found, demonstrating that deploying such analysis with any plasmonic optical fiber sensors can lead to sensing resolution improvements.
2023
Autores
Araujo, JCC; dos Santos, PSS; Dias, B; de Almeida, JMMM; Coelho, LCC;
Publicação
IEEE SENSORS JOURNAL
Abstract
The interrogation of optical fiber sensors (OFS) often relies on complex devices such as optical spectrum analyzers (OSAs) that are expensive with low portability and mainly suited to laboratory measurements or dedicated interrogation systems with limited spectral range. An interrogation unit was designed and fabricated using a photodetector combined with a micro-electromechanical system and a Fabry-Perot interferometer (MEMS-FPI) working as a tunable filter with a response in the range 1350-1650 nm. Deconvolution techniques were applied to mitigate the effect of the broadband response of the tunable filter on the measured signal. The performance of the unit was validated with the interrogation of long-period fiber gratings (LPFGs) as temperature, refractive index (RI), and relative humidity (RH) sensors. For the temperature, a sensitivity of 0.135 +/- 0.007 nm/degrees C was obtained, which showed a 4.9% relative error when compared to the same measurement with an OSA. For the RI, a sensitivity of 147 +/- 11 nm/RIU was obtained, which showed a relative error lower than 1% when compared to the OSA. For the humidity, sensitivities of 0.742 +/- 0.005 and 0.056 +/- 0.006 nm/%RH were obtained, with errors of 2.75% and 6.67%, respectively, when compared to a commercial dedicated interrogation system. The low relative error obtained when compared to commercial alternatives shows the potential of the system to be used in real-time applications that require portability, low cost, energy efficiency, and capacity for integration in dedicated systems.
2023
Autores
da Silva, PM; Mendes, JP; Coelho, LCC; de Almeida, JMMM;
Publicação
CHEMOSENSORS
Abstract
Reinforced concrete structures are prevalent in infrastructure and are of significant economic and social importance to humanity. However, they are prone to decay from cement paste carbonation. pH sensors have been developed to monitor cement paste carbonation, but their adoption by the industry remains limited. This work introduces two new methods for monitoring cement paste carbonation in real time that have been validated through the accelerated carbonation of cement paste samples. Both configurations depart from traditional pH monitoring. In the first configuration, the carbonation depth of a cement paste sample is measured using two CO2 optical fiber sensors. One sensor is positioned on the surface of the sample, while the other is embedded in the middle. As the carbonation depth progresses and reaches the embedded CO2 sensor, the combined response of the sensors changes. In the second configuration, a multimode fiber is embedded within the paste, and its carbonation is monitored by observing the increase in reflected light intensity (1.6-18%) resulting from the formation of CaCO3. Its applicability in naturally occurring carbonation is tested at concentrations of 3.2% CO2, and the influence of water is positively evaluated; thus, this setup is suitable for real-world testing and applications.
2023
Autores
dos Santos, SS; Mendes, J; de Almeida, MMM; Pastoriza Santos, I; Coelho, CC;
Publicação
Proceedings of SPIE - The International Society for Optical Engineering
Abstract
The increasing demand for precise chemical and biological sensing has led to the development of highly efficient plasmonic optical fiber sensors. Therefore, it is essential to optimize and match the operating wavelength region of both the optical fiber configuration and localized surface plasmon resonance of nanoparticles (NPs). This can be achieved by developing NPs that can reach resonance at near-infrared wavelengths, where refractive index sensitivity is enhanced, and silica optical fibers have lower losses. High aspect-ratio bimetallic Au@Ag nanorods and different side-polished fiber structures are tested using numerical simulations. The selected optical fiber configuration was based on a side-polished fiber with a 1 mm polished section. It is compared power losses and power at the NP interface for two configurations: a step-index single-mode fiber (SMF) with core/cladding diameters of 8.2/125 µm and a multimode graded-index fiber (GIF) with 62.5/125 µm at various polishing depths. The results showed that the best performance for both configurations was achieved at similar polishing depths, namely 59.5 and 55.2 µm for the SMF and GIF, respectively. The optical impact of retardation effects due to the proximity with the fiber structure were also observed, which caused a reduction in sensitivity from 1750 nm/RIU to 1500 nm/RIU and a red-shift of around 70 nm. © 2023 SPIE.
2023
Autores
Moura, D; Vilela, J; Saraiva, S; Monteiro-Silva, F; De Almeida, JMMM; Saraiva, C;
Publicação
FOODS
Abstract
The aim of this study was to assess the antimicrobial effects of myrtle (Myrtus communis L.) essential oil (EO) on pathogenic (E. coli O157:H7 NCTC 12900; Listeria monocytogenes ATCC BAA-679) and spoilage microbiota in beef and determine its minimum inhibitory concentration (MIC) and antioxidant activity. The behavior of LAB, Enterobacteriaceae, Pseudomonas spp., and fungi, as well as total mesophilic (TM) and total psychotropic (TP) counts, in beef samples, was analyzed during storage at 2 and 8 C-degrees in two different packaging systems (aerobiosis and vacuum). Leaves of myrtle were dried, its EO was extracted by hydrodistillation using a Clevenger-type apparatus, and the chemical composition was determined using chromatographical techniques. The major compounds obtained were myrtenyl acetate (15.5%), beta-linalool (12.3%), 1,8-cineole (eucalyptol; 9.9%), geranyl acetate (7.4%), limonene (6.2%), alpha-pinene (4.4%), linalyl o-aminobenzoate (5.8%), alpha-terpineol (2.7%), and myrtenol (1.2%). Myrtle EO presented a MIC of 25 mu L/mL for E. coli O157:H7 NCTC 12900, E. coli, Listeria monocytogenes ATCC BAA-679, Enterobacteriaceae, and E. coli O157:H7 ATCC 35150 and 50 mu L/mL for Pseudomonas spp. The samples packed in aerobiosis had higher counts of deteriorative microorganisms than samples packed under vacuum, and samples with myrtle EO presented the lowest microbial contents, indicating good antimicrobial activity in beef samples. Myrtle EO is a viable natural alternative to eliminate or reduce the pathogenic and deteriorative microorganisms of meat, preventing their growth and enhancing meat safety.
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