2023
Autores
dos Santos, SS; Mendes, P; Pastoriza Santos, I; de Almeida, MMM; Coelho, CC;
Publicação
Proceedings - 28th International Conference on Optical Fiber Sensors, OFS 2023
Abstract
Long-term stability and high scalability are significant issues in plasmonic optical fiber sensors. This work presents a highly scalable and low-cost all-chemical approach for production of gold-coated silver thin-films, ensuring high performance and chemical stability. © Optica Publishing Group 2023, © 2023 The Authors.
2023
Autores
Roberts, AA; Guimaraes, D; Tehrani, MW; Lin, S; Parsons, PJ;
Publicação
X-RAY SPECTROMETRY
Abstract
Portable X-Ray Fluorescence (XRF) has become increasingly popular where traditional laboratory methods are either impractical, time consuming, and/or too costly. While the Limit of Detection (LOD) is generally poorer for XRF compared to laboratory-based methods, recent advances have improved XRF LODs and increased its potential for field-based studies. Portable XRF can be used to screen food products for toxic elements such as lead (Pb), cadmium (Cd), mercury (Hg), arsenic (As), manganese, (Mn), zinc (Zn), and strontium (Sr). In this study, 23 seafood samples were analyzed using portable XRF in a home setting. After XRF measurements were completed in each home, the same samples were transferred to the laboratory for re-analysis using microwave-assisted digestion and Inductively Coupled Plasma Tandem Mass Spectrometry (ICP-MS/MS). Four elements (Mn, Sr, As, and Zn) were quantifiable by XRF in most samples, and those results were compared to those obtained by ICP-MS/MS. Agreement was judged reasonable for Mn, Sr, and As, but not for Zn. Discrepancies could be due to (1) the limited time available to prepare field samples for XRF, (2) the heterogeneous nature of real samples analyzed by XRF, and (3) the small beam spot size (similar to 1 mm) of the XRF analyzer. Portable XRF is a cost-effective screening tool for public health investigations involving exposure to toxic metals. It is important for practitioners untrained in XRF spectrometry to (1) recognize the limitations of portable instrumentation, (2) include validation data for each specific analyte(s) measured, and (3) ensure personnel have some training in sample preparation techniques for field-based XRF analyses.
2023
Autores
Perez Herrera, RA; Soares, L; Novais, S; Frazão, O; Silva, S;
Publicação
Proceedings of SPIE - The International Society for Optical Engineering
Abstract
2023
Autores
Robalinho, P; Rodrigues, A; Novais, S; Ribeiro, ABL; Silva, S; Frazão, O;
Publicação
EPJ Web of Conferences
Abstract
2023
Autores
Perez-Herrera, RA; Diaz, H; Soares, L; Novais, S; Lopez-Amo, M; Silva, S; Frazão, O;
Publicação
EPJ Web of Conferences
Abstract
2022
Autores
Cardoso, MP; Silva, AO; Romeiro, AF; Giraldi, MTR; Costa, JCWA; Santos, JL; Baptista, JM; Guerreiro, A;
Publicação
APPLIED SCIENCES-BASEL
Abstract
Subwavelength cells of metallic nanorods arrayed in a dielectric background, termed "metamaterials", present bulk properties that are useful to control and manipulate surface plasmon resonances. Such feature finds tremendous potential in providing a broad manifold of applications for plasmonic optical sensors. In this paper, we propose a surface-plasmon-resonance-based sensor with spectral response tunable by the volume fraction of silver present in a metamaterial layer deposited on a D-shaped photonic crystal fiber. Using computational simulations, we show that sensitivity and resolution can be hugely altered by changing the amount of constituents in the metamaterial, with no further modifications in the structure of the sensor. Moreover, the designed sensor can also be applied to label the average volume fraction of silver in the metamaterial layer and then to estimate its effective constitutive parameters.
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