Abstract
One way to mitigate the high costs of doing science or business at sea is to create technological infrastructures possessing all the skills and resources needed for successful maritime operations, and make those capabilities and skills available to the external entities requiring them. By doing so, the individual economic and scientific agents can be spared the enormous effort of creating and maintaining their own, particular set of equivalent capabilities, thus drastically lowering their initial operating costs. In addition to cost savings, operating based on fully-fledged, shared infrastructures not only allows the use of more advanced scientific equipment and highly skilled personnel, but it also enables the business teams (be it industry or research) to focus on their goals, rather than on equipment, logistics, and support. This paper will describe the TEC4SEA infrastructure, created precisely to operate as described. This infrastructure has been under implementation in the last few years, and has now entered its operational phase. This paper will describe it, present its current portfolio of services, and discuss the most relevant assets and facilities that have been recently acquired, so that the research and industrial communities requiring the use of such assets can fully evaluate their adequacy for their own purposes and projects.

Abstract
Laser-induced breakdown spectroscopy is a spectroscopic technique that allows for fast elemental mapping of heterogeneous samples. Yet, detailed maps need high-resolution sampling grids, which can turn the task into a time-consuming process and can increase sample damage. In this work, we present the implementation of an imaged-based intelligent mesh algorithm that makes use of superpixel segmentation to optimize elemental mapping processes. Our results show that the approach can increase the elemental mapping resolution and decrease acquisition times, fostering opportunities for applications that benefit from minimal sample damage such as heritage analysis, or timely analysis such as industrial applications. © 2022 The Author(s)

Abstract
Hydrogen peroxide is usually added to products to delay the development of microorganisms mainly in milk, hence increasing its stability over time, however the side effects can become devastating to human health.A technique is presented consisting of detecting hydrogen peroxide as an adulterant in milk through a sensor where pretreatment of the sample is not necessary, using a single use membrane. The detection of hydrogen peroxide in fresh-raw, whole, semi-skimmed and skimmed milk was performed using a luminol chem-iluminescence reaction.For hydrogen peroxide water solutions, a linear response was attained from 1.0 x 10-4 to 9.0 x 10-3 %w/w and an LOD (limit of detection) of 3.0 x 10-5 %w/w was determined. An R-squared value of 0.97 and a relative standard deviation lower than 10%, were achieved.Hydrogen peroxide concentration as low as 1.0 x 10-3 %w/w was measured for fresh-raw, skim and whole milk and for semi-skimmed milk, as low as 2.0 x 10-3 %w/w.The methodology presented, as long as our knowledge, is original, rapid, ecological and inexpensive. In regard of the sensitivity obtained, the methodology has great possibility to be applied in the detection of hydrogen peroxide in several areas. It is envisaged monitoring of food quality, agriculture systems and environment pollution.

Abstract
Imaging the spatial distribution of chemical elements at a sample surface is a common application of laserinduced breakdown spectroscopy with vast scientific and technological applications. Yet, typical imaging solutions only explore the creation of two-dimensional maps, which can limit the interpretability of the results and further diagnostics in three-dimensional settings. Within this context, this work explores the combination of spectral imaging techniques and photogrammetry to deploy a versatile solution for the creation of threedimensional spectral imaging models. First, by making use of a numerical algorithm that is able to match features in the spectral image with those of the three-dimensional model, we show how to match the mesh from distinct sensor modalities. Then, we describe a possible visualization workflow, making use of dedicated photogrammetry and visualization software to easily deploy interactive models. Overall, the results demonstrate the versatility of our approach and pave for the development of novel spectral imaging diagnostic strategies that are able to deliver better qualitative analysis and insight in the three-dimensional space.

Abstract
Over the past decade, molecular imprinting (MI) technologyhasmade tremendous progress, and the advancements in nanotechnology havebeen the major driving force behind the improvement of MI technology.The preparation of nanoscale imprinted materials, i.e., molecularlyimprinted polymer nanoparticles (MIP NPs, also commonly called nanoMIPs),opened new horizons in terms of practical applications, includingin the field of sensors. Currently, hydrogels are very promising forapplications in bioanalytical assays and sensors due to their highbiocompatibility and possibility to tune chemical composition, size(microgels, nanogels, etc.), and format (nanostructures, MIP film,fibers, etc.) to prepare optimized analyte-responsive imprinted materials.This review aims to highlight the recent progress on the use of hydrogelMIP NPs for biosensing purposes over the past decade, mainly focusingon their incorporation on sensing devices for detection of a fundamentalclass of biomolecules, the peptides and proteins. The review beginsby directing its focus on the ability of MIPs to replace biologicalantibodies in (bio)analytical assays and highlight their great potentialto face the current demands of chemical sensing in several fields,such as disease diagnosis, food safety, environmental monitoring,among others. After that, we address the general advantages of nanosizedMIPs over macro/micro-MIP materials, such as higher affinity towardtarget analytes and improved binding kinetics. Then, we provide ageneral overview on hydrogel properties and their great advantagesfor applications in the field of Sensors, followed by a brief descriptionon current popular routes for synthesis of imprinted hydrogel nanospherestargeting large biomolecules, namely precipitation polymerizationand solid-phase synthesis, along with fruitful combination with epitopeimprinting as reliable approaches for developing optimized protein-imprintedmaterials. In the second part of the review, we have provided thestate of the art on the application of MIP nanogels for screeningmacromolecules with sensors having different transduction modes (optical,electrochemical, thermal, etc.) and design formats for single use,reusable, continuous monitoring, and even multiple analyte detectionin specialized laboratories or in situ using mobiletechnology. Finally, we explore aspects about the development of thistechnology and its applications and discuss areas of future growth.

Abstract
Anode-less batteries are a promising innovation in energy storage technology, eliminating the need for traditional anodes and offering potential improvements in efficiency and capacity. Here, we have fabricated and tested two types of anode-less pouch cells, the first using solely a copper negative current collector and the other the same current collector but coated with a nucleation seed ZnO layer. Both types of cells used the same all-solid-state electrolyte, Li2.99Ba0.005ClO composite, in a cellulose matrix and a LiFePO4 cathode. Direct and indirect methods confirmed Li metal anode plating after charging the cells. The direct methods are X-ray photoelectron spectroscopy (XPS) and laser-induced breakdown spectroscopy (LIBS), a technique not divulged in the battery world but friendly to study the surface of the negative current collector, as it detects lithium. The indirect methods used were electrochemical cycling and impedance and scanning electron microscopy (SEM). It became evident the presence of plated Li on the surface of the current collector in contact with the electrolyte upon charging, both directly and indirectly. A maximum average lithium plating thickness of 2.9 mu m was charged, and 0.13 mu m was discharged. The discharge initiates from a maximum potential of 3.2 V, solely possible if an anode-like high chemical potential phase, such as Li, would form while plating. Although the ratings and energy densities are minor in this study, it was concluded that a layer of ZnO, even at 25 degrees C, allows for higher discharge power for more hours than plain Cu. It was observed that where Li plates on ZnO, Zn is not detected or barely detected by XPS. The present anode-less cells discharge quickly initially at higher potentials but may hold a discharge potential for many hours, likely due to the ferroelectric character of the electrolyte.