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Publicações

Publicações por CAP

2024

Ratiometric System based on an Ionic Liquid-Modified Colorimetric Dye for Enhanced Carbon Dioxide Sensing

Autores
Lopes, X; Coelho, CC; Jorge, AS; Mendes, P;

Publicação
2024 IEEE Sensors Applications Symposium, SAS 2024 - Proceedings

Abstract
Carbon dioxide (CO2) holds paramount significance in nature, serving as a vital component in Earth's ecosystems. Its evaluation has become increasingly important across various sectors, spanning from environmental conservation to industrial operations. Therefore, this study investigates the viability of utilizing a pH colorimetric dye as a C02-sensitive material. The material's effectiveness relies on chemical modifications induced in the dye structure through the action of a phase transfer agent, which establishes a stable equilibrium with the dye, thereby promoting its receptivity to C02 molecules. As the resulting physicochemical changes primarily exhibit colorimetric alterations, an optical system was developed to assess the performance of this material upon exposure to C02. Employing a dual-wavelength method, the system also incorporates a ratio metric relationship between the two signals to provide the most precise information. The conducted experiments generated promising results when the dye was subjected to varying concentrations of C02, ranging from 0% to 4 %, in comparison to nitrogen (N2). The application of the ratiometric method emerged as a crucial factor in this system, enabling its potential use in environments characterized by instability. Finally, the dye-sensitive characteristics experienced enhancement through the integration of an ionic liquid within the membrane matrix. © 2024 IEEE.

2024

Linear Fiber Laser Configurations for Optical Concentration Sensing in Liquid Solutions

Autores
Soares, L; Perez-Herrera, RA; Novais, S; Ferreira, A; Silva, S; Frazao, O;

Publicação
PHOTONICS

Abstract
In this study, different configurations based on linear fiber lasers were proposed and experimentally demonstrated to measure the concentration of liquid solutions. Samples of paracetamol liquid solutions with different concentrations, in the range from 52.61 to 201.33 g/kg, were used as a case-study. The optical gain was provided by a commercial bidirectional Erbium-Doped Fiber Amplifier (EDFA) and the linear cavity was obtained using two commercial Fiber Bragg Gratings (FBGs). The main difference of each configuration was the coupling ratio of the optical coupler used to extract the system signal. The sensing head corresponded to a Single-Mode Fiber (SMF) tip that worked as an intensity sensor. The results reveal that, despite the optical coupler used (50:50, 60:40, 70:30 or 80:20), all the configurations reached the laser condition, however, the concentration sensing was only possible using a laser drive current near to the threshold value. The configurations using a 70:30 and an 80:20 optical coupler allowed paracetamol concentration measurements with a higher sensitivity of (-3.00 +/- 0.24) pW/(g/kg) to be performed. In terms of resolution, the highest value obtained was 1.75 g/kg, when it was extracted at 20% of the output power to the linear cavity fiber laser configuration.

2024

Enhanced Sensitivity in Optical Sensors through Self-Image Theory and Graphene Oxide Coating

Autores
Cunha, C; Monteiro, C; Vaz, A; Silva, S; Frazao, O; Novais, S;

Publicação
SENSORS

Abstract
This paper presents an approach to enhancing sensitivity in optical sensors by integrating self-image theory and graphene oxide coating. The sensor is specifically engineered to quantitatively assess glucose concentrations in aqueous solutions that simulate the spectrum of glucose levels typically encountered in human saliva. Prior to sensor fabrication, the theoretical self-image points were rigorously validated using Multiphysics COMSOL 6.0 software. Subsequently, the sensor was fabricated to a length corresponding to the second self-image point (29.12 mm) and coated with an 80 mu m/mL graphene oxide film using the Layer-by-Layer technique. The sensor characterization in refractive index demonstrated a wavelength sensitivity of 200 +/- 6 nm/RIU. Comparative evaluations of uncoated and graphene oxide-coated sensors applied to measure glucose in solutions ranging from 25 to 200 mg/dL showed an eightfold sensitivity improvement with one bilayer of Polyethyleneimine/graphene. The final graphene oxide-based sensor exhibited a sensitivity of 10.403 +/- 0.004 pm/(mg/dL) and demonstrated stability with a low standard deviation of 0.46 pm/min and a maximum theoretical resolution of 1.90 mg/dL.

2024

A century on diameter measurement techniques in cylindrical structures

Autores
Cardoso, VHR; Caldas, P; Giraldi, MTR; Cernadas, ML; Fernandes, CS; Frazao, O; Costa, JCWA; Santos, JL;

Publicação
MEASUREMENT SCIENCE AND TECHNOLOGY

Abstract
This work addresses the historical development of techniques and methodologies oriented to the measurement of the internal diameter of transparent tubes since the original contributions of Anderson and Barr published in 1923 in the first issue of Measurement Science and Technology. The progresses on this field are summarized and highlighted the emergence and significance of the measurement approaches supported by the optical fiber.

2024

Optimizing Graphene Oxide Saturable Absorbers for Short Pulse Generation in Fiber Lasers: Characterization and Aging Assessment

Autores
Monteiro, CS; Perez-Herrera, RA; Silva, NA; Silva, SO; Frazao, O;

Publicação
FIBER LASERS AND GLASS PHOTONICS: MATERIALS THROUGH APPLICATIONS IV

Abstract
The generation of short pulses in fiber lasers using saturable absorbers made of graphene oxide (GO), focusing on film thickness, was studied and optimized. The saturable absorber comprised a GO thin film deposited onto a single-mode fiber using the spray coating technique. Water-dispersed GO with a concentration of 4 mg/mL, characterized by a high proportion of monolayer flakes, was employed. This thin film was integrated into a cavity ring laser featuring an erbium-doped fiber amplifier (EDFA), resulting in a fiber laser emitting at a central emission wavelength of approximately 1564 nm and having a total cavity length of approximately 120 m. By controlling intracavity polarization, short-pulsed light was generated through mode-locking, Q switching, or a combination of both regimes. This work presents a comprehensive characterization of the cavity ring laser operating under the mode-locking regime. It encompasses an analysis of the spectral behavior, focusing on the evolution of the Kelly's sidebands with increasing pump power, as well as an assessment of its temporal stability. Moreover, the effects of the aging of the saturable absorber material were studied after a time period of 6 months after the fabrication. It was observed that the general characteristics of spectral signal of the laser were maintained, with long-term stability .

2024

Coreless Silica Fiber Sensor based on Self-Image Theory and coated with Graphene Oxide

Autores
Cunha, C; Monteiro, C; Vaz, A; Silva, S; Frazao, O; Novais, S;

Publicação
OPTICAL SENSING AND DETECTION VIII

Abstract
This work provides a method that combines graphene oxide coating and self-image theory to improve the sensitivity of optical sensors. The sensor is designed specifically to measure the amount of glucose present quantitatively in aqueous solutions that replicate the range of glucose concentrations found in human saliva. COMSOL Multiphysics 6.0 was used to simulate the self-imaging phenomenon using a coreless silica fiber (CSF). For high-quality self-imaging, the second and fourth self-imaging points are usually preferred because of their higher coupling efficiency, which increases the sensor sensitivity. However, managing the fourth self-image is more difficult because it calls for a longer CSF length. As a result, the first and second self-image points were the focus of the simulation in this work. After the simulation, using the Layerby-Layer method, the sensor was constructed to a length that matched the second self-image point (29.12 mm) and coated with an 80 mu m/mL graphene oxide layer. When comparing uncoated and graphene oxide-covered sensors to measure glucose in liquids ranging from 25 to 200 mg/dL, one bilayer of polyethyleneimine/graphene demonstrated an eight-fold improvement in sensitivity. The final sensor, built on graphene oxide, showed stability with a low standard deviation of 0.6 pm/min. It also showed sensitivity at 10.403 +/- 0.004 pm/(mg/dL) with a limit of detection of 9.15 mg/dL.

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