2022
Autores
Dos Santos, PSS; Mendes, J; Dias, B; Pastoriza Santos, I; De Almeida, JMMM; Coelho, LCC;
Publicação
Journal of Physics: Conference Series
Abstract
New paths to increase the sensing performance of plasmonic sensors have been reported in recent years. There are several methodologies to achieve such purpose, namely by optimizing the nanostructure, nanomaterial and even the sensing platform. Recently the use nanoparticles over plasmonic thin films have been reported and shown sensitivity enhancement, when compared to a bare thin film. Nevertheless, a nanomaterial combination between NP and thin film has not been studied. In this work it was studied such plasmonic materials in order to optimize not only refractometric sensitivity but also decrease the resultant plasmonic band width. It was found that for Au, Ag and Cu thin films, the deposition of plasmonic nanoparticles resulted in an overall refractometric sensitivity and figure of merit (FOM) increase. The larger FOM increase was obtained for the Ag thin film, from 42 to 162 when coupled to Si nanoparticles. The greater sensitivity increase was achieved for a Cu thin film coupled to a Si nanoparticle, with an increase from 1745 to 3230 nm/RIU. © Published under licence by IOP Publishing Ltd.
2022
Autores
Araújo, JCC; Dias, B; Dos Santos, PSS; De Almeida, JMMM; Coelho, LCC;
Publicação
Journal of Physics: Conference Series
Abstract
The interrogation of optic fiber sensors usually relies in complex and costly equipment with low portability due to their size such as Optical Spectrum Analyzers (OSA) or high-resolution spectrometers. Because of this, micro spectrometer devices, such as Micro-Electromechanical Systems (MEMS) with Fabry-Pérot tunable filters, are emerging as simpler and compact alternatives capable of being used to acquire spectral information in a wide wavelength band. In this work it is described the development of an interrogation system capable of infrared spectroscopy using a MEMS Fabry-Pérot Interferometer (MEMS-FPI) with a spectral response in the 1350nm to 1650nm range. Its performance is tested with the interrogation of long period fiber gratings both as a refractive index sensor and as a temperature sensor. Deconvolution techniques such as Wiener filtering are used to reduce the impact of the tunable filter's impulse response in the measured signal. Results are comparable to those obtained using a typical OSA which shows the system's potential as a cheaper and more transportable alternative. © Published under licence by IOP Publishing Ltd.
2023
Autores
Dias, BS; De Almeida, JMMM; Coelho, LCC;
Publicação
OPTICS LETTERS
Abstract
The sensitivity of one-dimensional Bloch surface wave (BSW) sensors to external refractive index variations using Kretschmann's configuration is calculated analytically by employing first-order perturbation theory for both TE and TM modes. This approach is then validated by com- parison with both transfer matrix method simulations and experimental results for a chosen photonic crystal structure. Experimental sensitivities of (8.4 +/- 0.2)x102 and (8.4 +/- 0.4)x102 nm/RIU were obtained for the TE and TM BSW modes, corresponding to errors of 0.02% and 4%, respectively, when comparing with the perturbation the- ory approach. These results provide interesting insights into photonic crystal design for Bloch surface wave sensing by casting light into the important parameters related with sen- sor performance.(c) 2023 Optica Publishing Group
2023
Autores
Vasconcelos, H; Matias, A; Mendes, J; Araujo, J; Dias, B; Jorge, PAS; Saraiva, C; de Almeida, JMMM; Coelho, LCC;
Publicação
TALANTA
Abstract
Hydrogen peroxide is usually added to products to delay the development of microorganisms mainly in milk, hence increasing its stability over time, however the side effects can become devastating to human health.A technique is presented consisting of detecting hydrogen peroxide as an adulterant in milk through a sensor where pretreatment of the sample is not necessary, using a single use membrane. The detection of hydrogen peroxide in fresh-raw, whole, semi-skimmed and skimmed milk was performed using a luminol chem-iluminescence reaction.For hydrogen peroxide water solutions, a linear response was attained from 1.0 x 10-4 to 9.0 x 10-3 %w/w and an LOD (limit of detection) of 3.0 x 10-5 %w/w was determined. An R-squared value of 0.97 and a relative standard deviation lower than 10%, were achieved.Hydrogen peroxide concentration as low as 1.0 x 10-3 %w/w was measured for fresh-raw, skim and whole milk and for semi-skimmed milk, as low as 2.0 x 10-3 %w/w.The methodology presented, as long as our knowledge, is original, rapid, ecological and inexpensive. In regard of the sensitivity obtained, the methodology has great possibility to be applied in the detection of hydrogen peroxide in several areas. It is envisaged monitoring of food quality, agriculture systems and environment pollution.
2023
Autores
da Silva, PM; Coelho, LCC; de Almeida, JMMM;
Publicação
CHEMOSENSORS
Abstract
Water vapor sorption is a powerful tool for the analysis of cement paste, one of the most used substances by mankind. The monitoring of cementitious materials is fundamental for the improvement of infrastructure resilience, which has a deep impact on the economy, the environment, and on society. In this work, a multimode fiber was embedded in cement paste for real-time monitoring of cement paste water vapor sorption. Changes in the reflected light intensity due to the build-up of water in the cement paste's pores were exploited for this purpose. The sample was 7-day moist cured, and the relative humidity was controlled between 8.9% and 97.6%. Reflected light intensity was converted into a specific surface area of cement paste (133 m(2)/g) and thickness of water through the Brunauer-Emmett-Teller (BET) method and into a pore size distribution through the Barret-Joyner-Halenda (BJH) method. The results achieved through reflected light intensity agree with those found in the literature, validating the usage of this setup for the monitoring of water vapor sorption, breaking away from standard gravimetric measurements.
2023
Autores
Dos Santos, PSS; Mendes, JP; Dias, B; Perez-Juste, J; De Almeida, JMMM; Pastoriza-Santos, I; Coelho, LCC;
Publicação
SENSORS
Abstract
Biochemical-chemical sensing with plasmonic sensors is widely performed by tracking the responses of surface plasmonic resonance peaks to changes in the medium. Interestingly, consistent sensitivity and resolution improvements have been demonstrated for gold nanoparticles by analyzing other spectral features, such as spectral inflection points or peak curvatures. Nevertheless, such studies were only conducted on planar platforms and were restricted to gold nanoparticles. In this work, such methodologies are explored and expanded to plasmonic optical fibers. Thus, we study-experimentally and theoretically-the optical responses of optical fiber-doped gold or silver nanospheres and optical fibers coated with continuous gold or silver thin films. Both experimental and numerical results are analyzed with differentiation methods, using total variation regularization to effectively minimize noise amplification propagation. Consistent resolution improvements of up to 2.2x for both types of plasmonic fibers are found, demonstrating that deploying such analysis with any plasmonic optical fiber sensors can lead to sensing resolution improvements.
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