Abstract

Abstract
Long Period Fibre Gratings (LPFGs) were fabricated by femtosecond (fs) laser direct writing in a standard single-mode fibre (SMF-28e) to measure variations in the surrounding refractive index (SRI). The sensing sensitivity of these structures was optimized with the deposition of homogeneous thin layers of titanium dioxide (TiO2) by physical vapour deposition (PVD) process. A set of LPFGs were coated with different thickness layers of TiO2, and the spectral features were monitored for different SRI solutions. The wavelength shift and the optical power variation of the LPFG minimum attenuation band were measured achieving sensitivities of similar to 570 nm/RIU at using SRI near to 1.3600 in the case of the LPFG coated with 60 nm of TiO2, a 10-fold increase over the corresponding for a bare LPFG. For SRI values higher than the cladding refractive index, a sensitivity over similar to 3000 nm/RIU was determined for 30 nm of TiO2 thick film, a region where the bare LPFGs are useless. For 30 nm of TiO2, the optical power variation follows a quasi-linear function of the SRI, with a range of similar to 10 dB. Moreover, values as high as 50 and 120 dB/RIU at 1.3200 and 1.4200, respectively, can be obtained by choosing the proper film thickness. Preliminary studies revealed that coating fs-laser direct writing LPFGs with titanium dioxide improves their performance.

Abstract
Long period fiber gratings (LPFGs) were fabricated in a standard single mode fiber (SMF-28e) through femtosecond (fs) laser direct writing. LPFGs with longer and shorter periods were fabricated, which allows coupling from the fundamental core mode to lower and higher order asymmetric cladding modes (LP(1,6)and LP1,12, respectively). For the grating periods of 182.7 and 192.5 mu m, it was verified that the LP(1,12)mode exhibits a TAP at approximately 1380 and 1448 nm in air and water, respectively. Characterization of the LPFGs subjected to high-temperature thermal treatment was accomplished. Fine-tuning of the resonance band's position and thermal stability up to 600 degrees C was shown. The temperature sensitivity was characterized for the gratings with different periods and for different temperature ranges. A maximum sensitivity of -180.73, and 179.29 pm/degrees C was obtained for the two resonances of the 182.7 mu m TAP LPFG, in the range between 250 and 600 degrees C.

Abstract
Biogenic amines, such as putrescine are potential indicators of food storage condition and deterioration. The real time measurement of their concentration in food may become an important method of food control. It was found that putrescine diffuses through a thin layer made from a solution of Poly(ethylene-co-vinyl acetate) (PEVA) and maleic anhydride. Poly(ethylene-co-vinyl acetate) is a common non-chlorinated vinyl capable to adsorb specific analytes as putrescine which upon diffusion, reversibly binds to the maleic anhydride causing the polymer swelling resulting in spectral changes from the optical point of view. Long Period Fiber Gratings coated with 30 nm titanium dioxide, a high refractive index material used to increase the intrinsic sensitivity to the external refractive index, were overcoated with a thin layer of maleic anhydride doped Poly(ethylene-co-vinyl acetate). When exposed to solutions containing small concentrations of putrescine the resonant band corresponding to the LP1,6 cladding mode was found to move to shorter wavelengths. The observed blue shift corresponds to the increasing concentration of putrescine in the fiber sensor structure. Further work is being carried out to improve the sensitivity and the limit of detection of the sensing system as well as to increase range of operation, which is presently limited to 0.3 to 0.5 M.

Abstract
Near-surface optical waveguides were fabricated in alkaline earth boro-aluminosilicate glass (Eagle2000), by femtosecond laser direct writing, using two distinct approaches. First, the capability of directly inscribing optical waveguides close to the surface was tested, and then, compared to the adoption of post writing wet etching to bring to the surface waveguides inscribed at greater depths. Laser ablation was found to limit the minimum surface to core center distance to 6.5 mu m in the first method, with anisotropic wet etching limiting the latter to 3 mu m without any surface deformation; smaller separations can be achieved at the cost of the planar surface topography. Furthermore, the waveguide's cross-section was seen to vary for laser inscription nearing the surface, observations that were also corroborated by its distinct guiding characteristics when compared to the adoption of post writing wet etching. The spectral analysis (in the 500-1700 nm range) also evidenced an increase in insertion loss for longer wavelengths and smaller surface to core center separations, caused, most likely, by coupling loss due to the interaction between the propagating mode and the surface. Different lengths of waveguide exposed to the surface were also tested, revealing that scattering loss due to surface roughness is not an issue at the centimeter scale.

Abstract
The potential of evanescent Mach-Zehnder interferometers, embedded in Eagle2000 substrates, as refractive index sensors was assessed. For that, femtosecond laser direct writing and wet etching were used to fabricate and expose the sensing arm at the surface of the glass substrate, while keeping the reference arm buried. From the analysis of the structures' spectral response, we found that the wavelength shift of the different order peaks increased greatly for refractive indices nearing that of the glass, indicating a greater overlap between the guided mode's evanescent field and the external medium. Therefore, a maximum sensitivity of 10271 nm/RIU was obtained at a refractive index of 1.491. The sensitivity in the refractive index range of water-based solutions was, on the other hand, limited to 446 +/- 39 nm/RIU. Due to the geometry of the device, applications with films deposited at the surface of the substrate and PDMS based microfluidic channels can be explored.