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Publicações

Publicações por Marcos Martins

2016

Effect of anion type in the performance of ionic liquid/poly(vinylidene fluoride) electromechanical actuators

Autores
Mejri, R; Dias, JC; Hentati, SB; Martins, MS; Costa, CM; Lanceros Mendez, S;

Publicação
JOURNAL OF NON-CRYSTALLINE SOLIDS

Abstract
Low voltage actuators based on poly(vinylidene fluoride) (PVDF) with 10, 25 and 40% 1-hexyl-3-methylimidazolium chloride ([C(6)mim][Cl]) and 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C(6)mim][NTf2]) are prepared by solvent casting in order to evaluate the effect of anion size in the bending properties. Independently of the ionic liquid type and content, its presence leads to the crystallization of PVDF in the beta-phase. The addition of ionic liquid into the polymer matrix decreases significantly its degree of crystallinity and the elastic modulus. It is also confirmed the good miscibility between PVDF and IL, determined by the interaction of the CF2 groups from the PVDF chains with the imidazolium ring in the ionic liquid (IL). The AC conductivity of the composites depends both on the amount of ionic liquid content and anion size. The bending movement of the IL/PVDF composites is correlated to their degree of crystallinity, mechanical properties and ionic conductivity value and the best value of bending response (0.53%) being found for IL/PVDF composite with 40 wt of [C(6)min][Cl] at an applied voltage of 10 V square signal.

2019

Wideband and Wide Beam Polyvinylidene Difluoride (PVDF) Acoustic Transducer for Broadband Underwater (vol 19, 3991, 2019)

Autores
Martins, MS; Faria, CL; Matos, T; Goncalves, LM; Cabral, J; Silva, A; Jesus, SM;

Publicação
SENSORS

Abstract
The authors wish to make the following erratum to this paper [1]: Equations (1), (7), and (9) are incorrect and must be replaced by the following equations: [Formula presented] The authors apologize for this literal mistake, but emphasize that the content of the article is still correct, since all calculations were performed with the correct equations. The manuscript will be updated and the original will remain online on the article webpage, with a reference to this Erratum.

2019

Performance evaluation of a PVDF hydrophone for deep sea applications

Autores
Martins, MS; Faria, CL; Matos, T; Goncalves, LM; Silva, A; Jesus, SM; Cruz, N;

Publicação
OCEANS 2019 - Marseille, OCEANS Marseille 2019

Abstract
The lack of penetration of light and electromagnetic radiation beyond a few meters in the ocean makes acoustics the technique of choice for data transmission, target detection and ocean sensing in general. Acoustic transducers are typically based on piezoelectric materials due to the good response at high frequencies. Depending on the application it can be built using ceramics, polymers and composite materials. In the hydrostatic mode PZT ceramics hydrophones have low performance due to the low hydrostatic piezoelectric stress value. On the other hand, PVDF have shown relatively high hydrostatic mode response. This work presents the development of a PVDF hydrophone for deep sea applications. The hydrophone was subjected to a pressure test up to 25 MPa to evaluate the response variation under high hydrostatic pressure. The results show an increase up to 6 dB sensitivity under 15 MPa pressure.

2019

Optimization of an electromagnetic generator for underwater energy harvester

Autores
Faria, CL; Martins, MS; Lima, RA; Gonçalves, LM; Matos, T;

Publicação
OCEANS 2019 - Marseille, OCEANS Marseille 2019

Abstract
Energy harvesting devices can increase autonomy of submersible marine sensors. However, only the water movements can be used as energy source, since neither solar or temperature gradients are available bellow surface waters. A Linear Electromagnetic Generator (LEG), in a milliwatt energy harvester, is presented. Any moving parts are in contact with water, thus avoiding biofouling problems in the harvester. In this work, a 100mm length, 60mm diameter, cylindrical LEG was designed to maximize output power, and analyzed the effects of magnets size and geometry as well as coils position, at several working conditions. Two coils were used, with an internal resistance of 130 ? in 1500 turns, together with N38-N42 magnets. A mean electrical power of 25 mW (100 mW peak) was experimental measured in the optimized configuration, in realistic conditions, which is enough to power almost any electronic low-power sensor.

2019

A four-probe salinity sensor optimized for long-term autonomous marine deployments

Autores
Baptista, JP; Matos, T; Faria, CL; Magalhaes, VH; Vieira, EMF; Martins, MS; Goncalves, LM; Lopes, SF; Brito, FB;

Publicação
OCEANS 2019 - Marseille, OCEANS Marseille 2019

Abstract
Salinity measurement in water is typically performed with conductivity sensors. However, for long-term marine deployments, loss of precision is observed, mainly due to electrode drift (oxidation and degradation occurs in the presence of water, salts and bio-fouling), which results in inaccuracy of measurements. A cost-effective, low-power, four-probe salinity sensor is presented, to accurately measure long-term deployments in oceans, rivers and lakes. The four-probe methodology overcomes many of the drift problems, and the use of low-cost stainless-steel electrodes (avoiding platinum or titanium materials) can still achieve good long-term stability, in the practical salinity scale range from 2 to 42 PSU. Low-power electronics (200 µA in sleep-mode and 1 mA in active-mode) based on a ratiometric ADC conversion, and a low-power microcontroller with non-volatile memory, complements the proposed sensor, to achieve an autonomous salinity sensor for long-term marine deployments, with autonomy above 1 year with a 1 min-1 sample rate, using a common 2400 mA x 3.7 V lithium battery.

2017

High frequency wide beam PVDF ultrasonic projector for underwater communications

Autores
Martins M.S.; Barardo C.; Matos T.; Goncalves L.M.; Cabral J.; Silva A.; Jesus S.M.;

Publicação
OCEANS 2017 - Aberdeen

Abstract
This work describes the development and characterization of a wide beam and wideband ultrasonic transducer, designed as an emitter for underwater communications up to 1.5 MHz. The active element being used is composed of two layers of 110 µm PVDF (Polyvinylidene fluoride) film, with NiCu electrodes. The transducer has a semicircular shape with a diameter of 15 cm. Pool trials show a transmitting voltage response of approximately 150 dB re µPa/V 1m from 750kHz to 1MHz and higher than 130 dB re µPa/V 1m between 250kHz and 1.5MHz. At 1 MHz, when excited with 12V, the transducer has a power consumption of 37.5 mW.

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