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Publicações

Publicações por CRAS

2016

Saharan dust electrification perceived by a triangle of atmospheric electricity stations in Southern Portugal

Autores
Silva, HG; Lopes, FM; Pereira, S; Nicoll, K; Barbosa, SM; Conceicao, R; Neves, S; Harrison, RG; Collares Pereira, MC;

Publicação
JOURNAL OF ELECTROSTATICS

Abstract
Atmospheric Electric Potential Gradient (PG) measurements were carried out in three sites forming a triangular array in Southern Portugal. The campaign was performed during the summer, characterized by Saharan dust outbreaks; 16th-17th July 2014 dust event is considered. Short time-scale oscillations of the PG at two of the stations and a mid time-scale suppression of the PG in the three stations are found. Results are interpreted as evidencing long-range dust electrification; attributed to the air-Earth electrical current creating a bipolar charge distribution inside of the dust layer. The relevance of using arrays of sensors, instead of single sited, is highlighted.

2016

Phytoplankton composition of the water and gastrointestinal tract of the mussel Diplodon enno (Ortmann, 1921) from Sao Francisco river (Bahia, Brazil)

Autores
Alves, T; Lima, P; Lima, GMS; Cunha, MCC; Ferreira, S; Domingues, B; Machado, J;

Publicação
BRAZILIAN JOURNAL OF BIOLOGY

Abstract
The knowledge on diet composition of the freshwater mussel Diplodon enno (Ortmann) would aid in its culture and propagation allowing, this way, the replacement of natural endangered populations in Brazil. Microalgae are the main food source for captive mussels and unionids have displayed an ability to sort algae based on the cellular characteristics prior to ingestion. The main objective of the present work is to analyze the phytoplankton composition of the water from and of the gastrointestinal contents of the mussel D. enno, as an initial step for development of a suitable rearing diet. Therefore, water samples and bivalve specimens were collected from S. Francisco River, city of Paulo Afonso, Bahia, Brazil. The microalgal composition found in water and stomach/gut content samples was very diverse being represented by the following divisions: Cyanophyta, Chlorophyta, Dinophyta and Heterokontophyta (Diatoms). Concerning the relative abundance of microalgae divisions, it is possible to state, for the water and gastrointestinal contents, that Cyanophyta represents 15% and 14%, Chlorophyta 54% in both, Heterokontophyta 31% and 27% and Dinophyta 0% and 5%, respectively. According to the Brazilian CETESB criteria for phytoplankton species classification, 50% of Cyanophyta and 15% of Chlorophyta species observed in the water samples were classified as "very frequent", as were 68% of Heterokontophyta and 33% of Chlorophyta species in the gut/stomach tract samples. Focusing at a species level, although in the water only Coelastrum sp. and Chroococcus sp. were observed in 100% and 75% of the samples, respectively, in the gastrointestinal tract the species Staurastrum sp., Aulacoseira sp., Scenedesmus sp. and Fragilaria crotonensis occurred in 80% to 100% of the samples. The present results showed that D. enno feeds not only on small chlorophytes microalgae, due to their convenient size that facilitates higher feeding rates, but also on large size diatoms, due to a possible nutritional advantage for the bivalves. Thus, a diet composed by large diatoms and small chlorophytes microalgae may be considered as the most reasonable for the maintenance of D. enno populations.

2016

Aptamer-based fiber sensor for thrombin detection

Autores
Coelho, L; Marques Martins de Almeida, JMM; Santos, JL; da Silva Jorge, PAD; Martins, MCL; Viegas, D; Queiros, RB;

Publicação
JOURNAL OF BIOMEDICAL OPTICS

Abstract
The detection of thrombin based on aptamer binding is studied using two different optical fiber-based configurations: long period gratings coated with a thin layer of titanium dioxide and surface plasmon resonance devices in optical fibers coated with a multilayer of gold and titanium dioxide. These structures are functionalized and the performance to detect thrombin in the range 10 to 100 nM is compared in transmission mode. The sensitivity to the surrounding refractive index (RI) of the plasmonic device is higher than 3100 nmRIU(-1) in the RI range 1.335 to 1.355, a factor of 20 greater than the sensitivity of the coated grating. The detection of 10 nM of thrombin was accomplished with a wavelength shift of 3.5 nm and a resolution of 0.54 nM. (C) 2016 Society of Photo-Optical Instrumentation Engineers (SPIE)

2016

Characterization of zinc oxide coated optical fiber long period gratings with improved refractive index sensing properties

Autores
Coelho, L; Viegas, D; Santos, JL; de Almeida, JMMM;

Publicação
SENSORS AND ACTUATORS B-CHEMICAL

Abstract
A fiber-optic refractive index (RI) sensor based on a long period fiber grating (LPFG) coated with a zinc oxide (ZnO) thin film was fabricated and characterized. A method to overcoat the LPFG's with a homogeneous ZnO thin films was developed. Characterization of ZnO thin films, deposited simultaneously on silicon (Si) planar substrates, was performed using Scanning Electron Microscope, Energy Dispersive X-ray Spectroscopy and X-ray Photoelectron Spectroscopy. The LPFGs with ZnO coatings from 29 to 145 nm of thickness were characterized and compared in terms of the wavelength shift and the intensity of the attenuation bands changing the surrounding refractive index (SRI) from 1.300 to 1.600. An average wavelength sensitivity of similar to 7162 nm/RIU was achieved in the RI range from 1.440 to 1.456 and more than 12,000 nm/RIU at 1.440 RI. Using a ZnO film thickness of 116 nm and in the RI region between 1.320 and 1.360 the average sensitivity of similar to 806 nm/RIU was measured for a 145 nm thick film. Working as an intensity sensing device, the 87 nm coated LPFG shows a linear sensitivity of 216.4 dB/RIU in a wide range of RI from 1.340 to 1.420.

2016

Fabrication and Characterization of Metal Oxide-Coated Long-Period Fiber Gratings

Autores
Coelho, L; Santos, JL; Viegas, D; Marques Martins de Almeida, JMMM;

Publicação
JOURNAL OF LIGHTWAVE TECHNOLOGY

Abstract
Sensors based on long-period fiber gratings (LPFGs) over coated with metal oxide were fabricated and characterized for refractive index (RI) sensing. Oxidation of Ni, Ti, Al, and Cr was monitored in real time by following the features of the LPFG attenuation band. Themetals were deposited simultaneously on top of Si substrates for further chemical and morphological analysis. Wavelength sensitivities (nm/RIU) of about 10 437 at 1.432, 1150 at 1.400, 20 125 at 1.448, and 875 at 1.420 were achieved for LPFGs coated, with 68 nm of Ni, 60 nm of TiO2, 50 nm of Al2O3, and 62 nm of Cr2O3, respectively. For surrounding RI higher than the cladding RI, the wavelength sensitivities are 1937, 6801, 5762, and 3051 nm/RIU at 1.457 for the Ni, Ti, Al, and Cr oxides, respectively. Working as intensity sensing devices sensitivities up to 167 dB/RIU were measured. Metal oxide coated LPFGs leads to wavelength sensitivity enhancement comparing to bare LPFGs and may be used in systems with RI higher than the fiber cladding, a region where bare LPFGs are insensitive.

2016

Optical sensor based on hybrid FBG/titanium dioxide coated LPFG for monitoring organic solvents in edible oils

Autores
Coelho, L; Viegas, D; Santos, JL; de Almeida, JMMM;

Publicação
TALANTA

Abstract
A hybrid optical sensing scheme based on a fiber Bragg grating (FBG) combined with a titanium dioxide coated long period fiber grating (LPFG) for monitoring organic solvents in high refractive index edible oils is reported. In order to investigate and optimize the sensor performance, two different FBG/LPFG interrogation systems were investigated. The readout of the sensor was implemented using either the wavelength shift of the LPFG resonance dip or the variation in the optical power level of the reflected/transmitted light at the FBG wavelength peak, which in turn depends on the wavelength position of the LPFG resonance. Hexane concentrations up to 20%V/V, corresponding to the refractive index range from 1.451 to 1.467, were considered. For the transmission mode of operation, sensitivities of 1.41 nm/%V/V and 0.11 dB/%V/V, with resolutions of 0.58%V/V and 0.29%V/V, were achieved when using the LPFG wavelength shift and the FBG transmitted optical power, respectively. For the FBG reflection mode of operation, a sensitivity of 0.07 dB/V/V and a resolution better than 0.16%V/V were estimated.

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