Abstract
An optical fiber pH sensor based on a long-period fiber grating (LPFG) is reported. Two oppositely charged polymers, polyethylenimine (PEI) and polyacrylic acid (PAA), were alternately deposited on the sensing structure through a layer-by-layer (LbL) electrostatic self-assembly technique. Since the polymers are pH sensitive, their refractive index (RI) varies when the pH of the solution changes due to swelling/deswelling phenomena. The fabricated multilayer coating retained a similar property, enabling its use in pH-sensing applications. The pH of the PAA dipping solution was tuned so that a coated LPFG achieved a pH sensitivity of (6.3 +/- 0.2) nm/pH in the 5.92-9.23 pH range. Only two bilayers of PEI/PAA were used as an overlay, which reduces the fabrication time and increases the reproducibility of the sensor, and its reversibility and repeatability were demonstrated by tracking the resonance band position throughout multiple cycles between different pH solutions. With simulation work and experimental results from a low-finesse Fabry-Perot (FP) cavity on a fiber tip, the coating properties were estimated. When saturated at low pH, it has a thickness of 200 nm and 1.53 +/- 0.01 RI, expanding up to 310 nm with a 1.35 +/- 0.01 RI at higher pH values, mostly due to the structural changes in the PAA.

Abstract
The increasing adoption of robotic solutions for inspection tasks in challenging environments is becoming increasingly prevalent, particularly in the offshore wind energy industry. This trend is driven by the critical need to safeguard the integrity and operational efficiency of offshore infrastructure. Consequently, the design of inspection vehicles must comply with rigorous requirements established by the offshore Operation and Maintenance (O&M) industry. This work presents the design of an autonomous surface vehicle (ASV), named Nautilus, specifically tailored to withstand the demanding conditions of offshore O&M scenarios. The design encompasses both hardware and software architectures, ensuring Nautilus's robustness and adaptability to the harsh maritime environment. It presents a compact hull capable of operating in moderate sea states (wave height up to 2.5 m), with a modular hardware and software architecture that is easily adapted to the mission requirements. It has a perception payload and communication system for edge and real-time computing, communicates with a Shore Control Center and allows beyond visual line-of-sight operations. The Nautilus software architecture aims to provide the necessary flexibility for different mission requirements to offer a unified software architecture for O&M operations. Nautilus's capabilities were validated through the professional testing process of the ATLANTIS Test Center, involving operations in both near-real and real-world environments. This validation process culminated in Nautilus's reaching a Technology Readiness Level 8 and became the first ASV to execute autonomous tasks at a floating offshore wind farm located in the Atlantic.

Abstract
In online three-dimensional packing problems (3D-PPs), unlike offline problems, items arrive sequentially and require immediate packing decisions without any information about the quantities and sizes of the items to come. Heuristic methods are of great importance in solving online problems to find good solutions in a reasonable amount of time. However, the literature on heuristics for online problems is sparse. As our first contribution, we developed a pool of heuristics applicable to online 3D-PPs with complementary performance on different sets of instances. Computational results showed that in terms of the number of used bins, in all problem instances, at least one of our heuristics had a better or equal performance compared to existing heuristics in the literature. The developed heuristics are also fully applicable to an intermediate class between offline and online problems, referred to in this paper as a specific type of semi-online with full look-ahead, which has several practical applications. In this class, as in offline problems, complete information about all items is known in advance (i.e., full look-ahead); however, due to time or space constraints, as in online problems, items should be packed immediately in the order of their arrival. As our second contribution, we presented an algorithm selection framework, building on developed heuristics and utilizing prior information about items in this specific class of problems. We used supervised machine learning techniques to find the relationship between the features of problem instances and the performance of heuristics and to build a prediction model. The results indicate an 88% accuracy in predicting (identifying) the most promising heuristic(s) for solving any new instance from this class of problems.

Abstract
The excitation of two different electromagnetic surface waves-surface plasmon polaritons (SPPs) and Bloch surface waves (BSWs)-is demonstrated in a 1-D metal-dielectric photonic crystal with numerical and experimental studies. The discussed structure consists of an Ag-TiO2 thin-film stack forming a metal-insulator-metal-insulator device. The thickness of the TiO2 layer placed between the metals is tested for two different values (50 and 300 nm), which also allows the excitation of guided-mode resonances. It is observed that BSWs in this metal-dielectric structure behave similar to the case of all-dielectric photonic crystals, whereas the SPP modes display similar properties to those excited in metal-insulator-metal cavities. The sensitivity of these surface states to variations in the refractive index (RI) of the external dielectric is characterized. For the case of the plasmonic modes, a maximum sensitivity of (7.2 +/- 0.3) x 10(3) nm/RIU was measured, while for the BSW the maximum sensitivity was (1.20 +/- 0.05) x 10(2) nm/RIU. Due to the large field enhancement and penetration on external media, these surface states display exceptional properties for application in optical sensors, and the presented results provide interesting possibilities in the design of novel sensing structures with a flexible selection of surface states for interrogation.

Abstract
Composites of poly(vinyl alcohol) (PVA) in the shape of braids, in combination with crystals of hydroxyapatite (HAp), were analyzed to perceive the influence of this bioceramic on both the quasi-static and viscoelastic behavior under tensile loading. Analyses involving energy-dispersive X-ray spectroscopy (EDS) and scanning electron microscopy (SEM) allowed us to conclude that the production of a homogeneous layer of HAp on the braiding surface and the calcium/phosphate atomic ratio were comparable to those of natural bone. The maximum degradation temperature established by thermogravimetric analysis (TGA) showed a modest decrease with the addition of HAp. By adding HAp to PVA braids, an increase in the glass transition temperature (Tg) is noticed, as demonstrated by dynamic mechanical analysis (DMA) and differential thermal analysis (DTA). The PVA/HAp composite braids' peaks were validated by Fourier transform infrared (FTIR) spectroscopy to be in good agreement with common PVA and HAp patterns. PVA/HAp braids, a solution often used in the textile industry, showed superior overall mechanical characteristics in monotonic tensile tests. Creep and relaxation testing showed that adding HAp to the eight and six-braided yarn architectures was beneficial. By exhibiting good mechanical performance and most likely increased biological qualities that accompany conventional care for bone applications in the fracture healing field, particularly multifragmentary ones, these arrangements can be applied as a fibrous fixation system.

Abstract
The exponential growth in the digitisation of services implies the handling and storage of large volumes of data. Businesses and services see data sharing and crossing as an opportunity to improve and produce new business opportunities. The health sector is one area where this proves to be true, enabling better and more innovative treatments. Notwithstanding, this raises concerns regarding personal data being treated and processed. In this paper, we present a patient-centric platform for the secure sharing of health records by shifting the control over the data to the patient, therefore, providing a step further towards data sovereignty. Data sharing is performed only with the consent of the patient, allowing it to revoke access at any given time. Furthermore, we also provide a break-glass approach, resorting to Proxy Re-encryption (PRE) and the concept of a centralised trusted entity that possesses instant access to patients' medical records. Lastly, an analysis is made to assess the performance of the platform's key operations, and the impact that a PRE scheme has on those operations.